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Key Documents

226548

Sigma-Aldrich

Silver perchlorate hydrate

99%

Synonym(s):

Perchloric acid silver hydrate, Silver perchlorate monohydrate

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About This Item

Empirical Formula (Hill Notation):
AgClO4 · xH2O
CAS Number:
Molecular Weight:
207.32 (anhydrous basis)
EC Number:
MDL number:
UNSPSC Code:
12352302
PubChem Substance ID:
NACRES:
NA.23

assay

99%

form

crystalline

reaction suitability

reagent type: oxidant

mp

485 °C (lit.)

storage temp.

2-8°C

SMILES string

O.[Ag+].[O-]Cl(=O)(=O)=O

InChI

1S/Ag.ClHO4.H2O/c;2-1(3,4)5;/h;(H,2,3,4,5);1H2/q+1;;/p-1

InChI key

IXFNJWPLHOWEPT-UHFFFAOYSA-M

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Application

Used to prepare silver 3,3′-dicyanodiphenylacetylene coordination networks for study of the effect of ligands on network structure toward the goal of engineering novel materials.

pictograms

Flame over circleCorrosion

signalword

Danger

hcodes

Hazard Classifications

Eye Dam. 1 - Ox. Sol. 2 - Skin Corr. 1B

Storage Class

5.1A - Strongly oxidizing hazardous materials

wgk_germany

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges


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Keith A. Hirsch et al.
Inorganic chemistry, 36(14), 2960-2968 (1997-07-02)
Coordination networks of 3,3'-dicyanodiphenylacetylene (3,3'-DCPA, 1) with silver(I) salts characterized by single-crystal X-ray analysis are described. Network topology is found to depend on both the counterion and solvent employed during crystallization. The conformation adopted by the ligand varies between planar

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