222380
Allylpalladium(II) chloride dimer
98%
Synonym(s):
Bis((η3-allyl)(chloro)palladium), Di-ο-allyldi-μ-chlorodipalladium, [PdCl(C3H5)]2
About This Item
Recommended Products
Quality Level
assay
98%
form
solid
reaction suitability
core: palladium
reaction type: Cross Couplings
reagent type: catalyst
reaction type: C-H Activation
greener alternative product characteristics
Catalysis
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Greener Alternative Product
greener alternative category
, Aligned
storage temp.
2-8°C
SMILES string
Cl[Pd]CC=C.Cl[Pd]CC=C
InChI
1S/2C3H5.2ClH.2Pd/c2*1-3-2;;;;/h2*3H,1-2H2;2*1H;;/q;;;;2*+1/p-2
InChI key
TWKVUTXHANJYGH-UHFFFAOYSA-L
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General description
Application
- Synthesis of cationic palladium cataysts, used in the microwave-assisted Heck arylation.
- Synthesis of N-heterocyclic carbene-palladium-η3-allyl chloride complexes, which are efficient catalyst for the Suzuki-Miyaura cross-coupling of aryl bromides and activated aryl chlorides.
- Synthesis of 1,4-diallyl-1,2-dihydroisoquinolines.
- As catalyst for greener Buchwald-Hartwig coupling in TPGS-750-M.
On the Way Towards Greener Transition-Metal-Catalyzed Processes as Quantified by E Factors
signalword
Warning
hcodes
Hazard Classifications
Skin Irrit. 2
Storage Class
11 - Combustible Solids
wgk_germany
WGK 3
ppe
dust mask type N95 (US), Eyeshields, Faceshields, Gloves
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Articles
TPGS-750-M, a second generation surfactant, is useful for room temperature, palladium and ruthenium-catalyzed reactions in water. Reactions include the Heck reaction, Suzuki-Miyaura reaction, Sonogashira reaction, Buchwald-Hartwig amination reaction, Negishi reaction, and olefin metathesis.
The Heck reaction is the palladium catalyzed cross-coupling reaction between alkenes and aryl or vinyl halides (or triflates) to afford substituted alkenes.
Protocols
TPGS-750-M, a second generation surfactant, may be used in the Buchwald-Hartwig Amination Reaction in Water at Room Temperature.
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