499382

2-Pyridylzinc bromide solution

0.5 M in THF

• Synonym(s): Bromo-2-pyridinylzinc, Pyridin-2-ylzinc bromide
• Empirical Formula (Hill Notation): C₅H₄BrNZn
• CAS Number: 218777-23-2
• Molecular Weight: 223.39
• MDL number: MFCD00671985
• UNSPSC Code: 12352103
• PubChem Substance ID: 24873276
• NACRES: NA.22

Properties

• Quality Level: 100
• concentration: 0.5 M in THF
• density: 0.974 g/mL at 25 °C
• storage temp.: 2-8°C
• SMILES string: Br[Zn]c1ccccn1
• InChI: 1S/C5H4N.BrH.Zn/c1-2-4-6-5-3-1;;/h1-4H;1H;/q;;+1/p-1
• InChI key: XYTLXTHDABUPLT-UHFFFAOYSA-M

Description

Application

Used in the preparation of P,N ligands for asymmetric Ir-catalyzed reactions.

Legal Information

Product of Rieke Metals, Inc.
Rieke is a registered trademark of Rieke Metals, Inc.

Safety Information

• pictograms: GHS02,GHS08,GHS05,GHS07
• signalword: Danger
• hcodes: H225,H261,H302,H314,H335,H351
• pcodes: P210 - P231 + P232 - P280 - P370 + P378 - P402 + P404 - P403 + P235
• Hazard Classifications: Acute Tox. 4 Oral - Carc. 2 - Flam. Liq. 2 - Skin Corr. 1B - STOT SE 3 - Water-react 2
• target_organs: Respiratory system
• supp_hazards: EUH019
• Storage Class: 4.3 - Hazardous materials which set free flammable gases upon contact with water
• wgk_germany: WGK 3
• flash_point_f: 1.0 °F - closed cup
• flash_point_c: -17.2 °C - closed cup
• ppe: Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter