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Merck

87920

Supelco

Tetramethylsilane

analytical standard, for NMR spectroscopy, ACS reagent

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About This Item

Wzór liniowy:
Si(CH3)4
Numer CAS:
Masa cząsteczkowa:
88.22
Beilstein:
1696908
Numer WE:
Numer MDL:
Kod UNSPSC:
12142201
Identyfikator substancji w PubChem:
NACRES:
NA.24

klasa czystości

ACS reagent
analytical standard
for NMR spectroscopy

Poziom jakości

ciśnienie pary

11.66 psi ( 20 °C)

Próba

≥99.5% (GC)

Postać

liquid

temp. samozapłonu

842 °F

współczynnik refrakcji

n20/D 1.358 (lit.)
n20/D 1.359

tw

26-28 °C (lit.)

mp

−99 °C (lit.)

gęstość

0.648 g/mL at 25 °C (lit.)

Zastosowanie

environmental

format

neat

temp. przechowywania

2-8°C

ciąg SMILES

C[Si](C)(C)C

InChI

1S/C4H12Si/c1-5(2,3)4/h1-4H3

Klucz InChI

CZDYPVPMEAXLPK-UHFFFAOYSA-N

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Opis ogólny

Tetramethylsilane has been recommended by the International Union of Pure and Applied Chemistry (IUPAC) as a universal reference for all nuclides. It is commonly used as a reference standard in nuclear magnetic resonance (NMR) for measuring proton chemical shifts and the temperature dependence of the 1H chemical shift of TMS in solvents such as chloroform, methanol, and dimethylsulfoxide is studied.

Zastosowanie

Tetramethylsilane may be used as an internal standard for the quantitative analysis of medicinal plant extracts and herbal products using the quantitative NMR (qNMR) method. It may also be used as an internal standard to investigate peroxide-based chemical systems for the crosslinking reactions carried on isotactic polypropylene using FT-IR spectrometry and proton nuclear magnetic resonance (1H NMR) techniques.
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Piktogramy

Flame

Hasło ostrzegawcze

Danger

Zwroty wskazujące rodzaj zagrożenia

Zwroty wskazujące środki ostrożności

Klasyfikacja zagrożeń

Flam. Liq. 1

Kod klasy składowania

3 - Flammable liquids

Klasa zagrożenia wodnego (WGK)

WGK 3

Temperatura zapłonu (°F)

-16.6 °F - closed cup

Temperatura zapłonu (°C)

-27 °C - closed cup

Środki ochrony indywidualnej

Eyeshields, Faceshields, Gloves


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Ramesh C Sharma et al.
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The decomposition of trimethylsilane and tetramethylsilane has been investigated for the first time, using hot wire (catalytic) at various temperatures. Trimethylsilane is catalytic-dissociated in these species SiH(2), CH(3)SiH, CH(3), CH(2)Si. Time of flight mass spectroscopy signal of these species are
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First measurements with a prototype ionization chamber are described to be applied in online monitoring of modulated fields in radiation therapy. The liquids isooctane, isononane (TMP) and tetramethylsilane (TMS) are used in a high purity grade in order to realize
Robin K Harris et al.
Magnetic resonance in chemistry : MRC, 45 Suppl 1, S174-S186 (2007-12-25)
Computations for chemical shifts of molecular organic compounds using the gauge-including projector augmented wave method and the NMR-CASTEP code are reviewed. The methods are briefly introduced, and some general aspects involving the sources of uncertainty in the results are explored.
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The chemical shift of TMS is commonly assumed to be zero. However, it varies by over 1 ppm for 1H and 4 ppm for 13C and shows a correlation with the physical properties of the solvent. Using the commonly accepted
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