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About This Item
Wzór empiryczny (zapis Hilla):
C10H10O
Numer CAS:
Masa cząsteczkowa:
146.19
Numer MDL:
Kod UNSPSC:
12352100
Identyfikator substancji w PubChem:
NACRES:
NA.22
Polecane produkty
Poziom jakości
Próba
99%
Postać
liquid
współczynnik refrakcji
n20/D 1.555 (lit.)
tw
93-95 °C/4 mmHg (lit.)
gęstość
1.064 g/mL at 25 °C (lit.)
grupa funkcyjna
ketone
ciąg SMILES
CC1Cc2ccccc2C1=O
InChI
1S/C10H10O/c1-7-6-8-4-2-3-5-9(8)10(7)11/h2-5,7H,6H2,1H3
Klucz InChI
BEKNOGMQVKBMQN-UHFFFAOYSA-N
Opis ogólny
2-Methyl-1-indanone, a α-benzocycloalkenone, is a derivative of 1-indanone. Its synthesis has been reported. The enzymatic dynamic kinetic resolution (DKR) of racemic 2-methyl-1-indanone has been studied. The asymmetric α-arylation and hydroxymethylation of 2-methyl-1-indanone has been reported. It participated in the synthesis of 2-methyl-6-carboxyazulene.
Zastosowanie
2-Methyl-1-indanone may be used as a starting material in the synthesis of β-benzocycloalkenone. It may be used in the synthesis of the following:
- cyclohex-2-en-1-yl 2-methyl-1H-inden-3-yl carbonate
- 2-hydroxy-2-methyl-1-indanone
- O-alkoxycarbonylation of lithium enolates
This page may contain text that has been machine translated.
Kod klasy składowania
10 - Combustible liquids
Klasa zagrożenia wodnego (WGK)
WGK 3
Temperatura zapłonu (°F)
Not applicable
Temperatura zapłonu (°C)
Not applicable
Środki ochrony indywidualnej
Eyeshields, Gloves
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Dokumenty związane z niedawno zakupionymi produktami zostały zamieszczone w Bibliotece dokumentów.
Michael W Justik et al.
Molecules (Basel, Switzerland), 10(1), 217-225 (2007-11-17)
The conversion of alpha-benzocycloalkenones to homologous beta-benzocyclo-alkenones containing six, seven and eight-membered rings is reported. This was accomplished via a Wittig olefination-oxidative rearrangement sequence using[hydroxy(tosyloxy)iodo]-benzene (HTIB) is the oxidant, that enables the synthesis of regioisomeric pairs of methyl-substituted beta-benzocycloalkenones. The
Cyclophanes. 9. anti-[2.2](2, 6) Azulenophane. Synthesis and charge-transfer interaction.
Luhowy R and Keehn PM.
Journal of the American Chemical Society, 99(11), 3797-3805 (1977)
On the decarboxylation of 2-methyl-1-tetralone-2-carboxylic acid-oxidation of the enol intermediate by triplet oxygen.
Riahi A, et al.
New. J. Chem., 37(8), 2245-2249 (2013)
Taku Kitanosono et al.
Chemistry, an Asian journal, 10(1), 133-138 (2014-10-29)
Enzymes exhibit overwhelmingly superior catalysis compared with artificial catalysts. Current strategies to rival enzymatic catalysis require unmodified or minimally modified structures of active sites, gigantic molecular weight, and sometimes the use of harsh conditions such as extremely low temperatures in
Selective and easy preparation of enol carbonates of α-disubstituted aryl ketones from their lithium enolates.
Aboulhoda SJ, et al.
Tetrahedron Letters, 36(27), 4795-4796 (1995)
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