795666

Garg 5-bromo-3,4-pyridyne precursor

95%

• 동의어(들): 5-Bromo-4-(trimethylsilyl)pyridin-3-yl trifluoromethanesulfonate
• 실험식(Hill 표기법): C₉H₁₁BrF₃NO₃SSi
• CAS Number: 1413439-82-3
• Molecular Weight: 378.24
• MDL number: MFCD25976537
• UNSPSC 코드: 12352100
• PubChem Substance ID: 329768500
• NACRES: NA.22

속성

• Quality Level: 100
• 분석: 95%
• 형태: liquid
• density: 1.549 g/L at 25 °C
• 작용기: bromo; fluoro; triflate
• 저장 온도: 2-8°C
• SMILES string: BrC1=CN=CC(S(=O)(C(F)(F)F)=O)=C1[Si](C)(C)C
• InChI: 1S/C9H11BrF3NO3SSi/c1-19(2,3)8-6(10)4-14-5-7(8)17-18(15,16)9(11,12)13/h4-5H,1-3H3
• InChI key: DFTOVRWLXREECB-UHFFFAOYSA-N

설명

애플리케이션

Pyridyne precursor can be activated under mild fluoride conditions, which are highly reactive with dienes and other dipolariphiles (e.g. azides) to provide cycloaddition products containing an indole motif.

기타 정보

Indolyne Experimental and Computational Studies: Synthetic Applications and Origins of Selectivities of Nucleophilic Additions

Regioselective reactions of 3; 4-pyridynes enabled by the aryne distortion model

안전성 정보

• 픽토그램: GHS06,GHS05
• 신호어: Danger
• 유해 및 위험 성명서: H301,H315,H318,H335
• 예방조치 성명서: P280 - P301 + P310 + P330 - P302 + P352 - P305 + P351 + P338 + P310
• Hazard Classifications: Acute Tox. 3 Oral - Eye Dam. 1 - Skin Irrit. 2 - STOT SE 3
• 표적 기관: Respiratory system
• Storage Class Code: 6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects
• WGK: WGK 3
• Flash Point (°F): Not applicable
• Flash Point (°C): Not applicable