795674

3-(Trimethylsilyl)pyridin-2-yl trifluoromethanesulfonate

95%

• 동의어(들): Garg 2,3-pyridyne precursor
• 실험식(Hill 표기법): C₉H₁₂F₃NO₃SSi
• CAS Number: 134391-76-7
• Molecular Weight: 299.34
• MDL number: MFCD18257067
• UNSPSC 코드: 12352100
• PubChem Substance ID: 329768501
• NACRES: NA.22

속성

• Quality Level: 100
• 분석: 95%
• 양식: liquid
• refractive index: n/D 1.454
• density: 1.266 at 25 °C
• 작용기: fluoro; triflate
• 저장 온도: 2-8°C
• SMILES string: [Si](C)(C)(C)c1c(nccc1)O[S](=O)(=O)C(F)(F)F
• InChI: 1S/C9H12F3NO3SSi/c1-18(2,3)7-5-4-6-13-8(7)16-17(14,15)9(10,11)12/h4-6H,1-3H3
• InChI key: SXIBFUWSBRRXRJ-UHFFFAOYSA-N

설명

애플리케이션

Pyridyne precursor can be activated under mild fluoride conditions; which are highly reactive with dienes and other dipolariphiles (e.g. azides) to provide cycloaddition products containing an indole motif.

기타 정보

Indolyne Experimental and Computational Studies: Synthetic Applications and Origins of Selectivities of Nucleophilic Additions

Regioselective reactions of 3; 4-pyridynes enabled by the aryne distortion model

안전성 정보

• 픽토그램: GHS05,GHS07
• 신호어: Danger
• 유해 및 위험 성명서: H315,H318,H335
• 예방조치 성명서: P280 - P302 + P352 - P305 + P351 + P338 + P310
• Hazard Classifications: Eye Dam. 1 - Skin Irrit. 2 - STOT SE 3
• 표적 기관: Respiratory system
• Storage Class Code: 10 - Combustible liquids
• WGK: WGK 3
• Flash Point (°F): Not applicable
• Flash Point (°C): Not applicable