728365
1-[(Triisopropylsilyl)ethynyl]-1,2-benziodoxol-3(1H)-one
≥98.0% (AT)
동의어(들):
1-{[Tris-(1-methylethyl)silyl]ethynyl]}-1,2-benziodoxol-3(1H)-one, TIPS-EBX
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모든 사진(2)
About This Item
실험식(Hill 표기법):
C18H25IO2Si
CAS Number:
Molecular Weight:
428.38
MDL number:
UNSPSC 코드:
12352005
PubChem Substance ID:
NACRES:
NA.22
추천 제품
분석
≥98.0% (AT)
양식
crystals
반응 적합성
reaction type: C-C Bond Formation
작용기
iodo
SMILES string
CC(C)[Si](C#C[I]1OC(=O)c2ccccc12)(C(C)C)C(C)C
InChI
1S/C18H25IO2Si/c1-13(2)22(14(3)4,15(5)6)12-11-19-17-10-8-7-9-16(17)18(20)21-19/h7-10,13-15H,1-6H3
InChI key
NTHGHMCOPNSZIR-UHFFFAOYSA-N
애플리케이션
Introduction of silylacetylenes
포장
Bottomless glass bottle. Contents are inside inserted fused cone.
신호어
Warning
유해 및 위험 성명서
Hazard Classifications
Aquatic Chronic 4 - Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
표적 기관
Respiratory system
Storage Class Code
11 - Combustible Solids
WGK
WGK 3
Flash Point (°F)
Not applicable
Flash Point (°C)
Not applicable
가장 최신 버전 중 하나를 선택하세요:
이미 열람한 고객
Stefano Nicolai et al.
Organic letters, 12(2), 384-387 (2009-12-17)
The first example of intramolecular oxyalkynylation of nonactivated alkenes using oxidative Pd chemistry is reported. Both phenol and aromatic or aliphatic acid derivatives could be used under operator-friendly conditions (room temperature, technical solvents, under air). The discovery of the superiority
Direct alkynylation of thiophenes: cooperative activation of TIPS-EBX with gold and Brønsted acids.
Jonathan P Brand et al.
Angewandte Chemie (International ed. in English), 49(40), 7304-7307 (2010-08-24)
Direct alkynylation of indole and pyrrole heterocycles.
Jonathan P Brand et al.
Angewandte Chemie (International ed. in English), 48(49), 9346-9349 (2009-11-07)
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