677892
Tetrakis(acetonitrile)copper(I) tetrafluoroborate
97%
동의어(들):
Cu(MeCN)4BF4, Copper(I) tetra(acetonitrile) tetrafluoroborate, Tetra(acetonitrile)copper(1+) tetrafluoroborate
로그인조직 및 계약 가격 보기
모든 사진(2)
About This Item
실험식(Hill 표기법):
C8H12BCuF4N4
CAS Number:
Molecular Weight:
314.56
MDL number:
UNSPSC 코드:
12161600
PubChem Substance ID:
NACRES:
NA.22
추천 제품
![Tris[(1-benzyl-1H-1,2,3-triazol-4-yl)methyl]amine 97%](/deepweb/assets/sigmaaldrich/product/structures/179/695/86a721c8-2a4c-4e4f-bc36-6276ce7a941f/640/86a721c8-2a4c-4e4f-bc36-6276ce7a941f.png)
Quality Level
분석
97%
형태
solid
반응 적합성
core: copper
reagent type: catalyst
환경친화적 대안 제품 특성
Catalysis
Learn more about the Principles of Green Chemistry.
sustainability
Greener Alternative Product
환경친화적 대안 카테고리
SMILES string
[Cu+].CC#N.CC#N.CC#N.CC#N.F[B-](F)(F)F
InChI
1S/4C2H3N.BF4.Cu/c4*1-2-3;2-1(3,4)5;/h4*1H3;;/q;;;;-1;+1
InChI key
YZGSKMIIVMCEFE-UHFFFAOYSA-N
일반 설명
We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for catalytic efficiency. Click here for more information.
애플리케이션
Catalyst for greener oxidation of alcohols under aerobic conditions.
Copper(I)/TEMPO-catalyzed aerobic oxidation of primary alcohols to aldehydes with ambient air
Copper(I)/TEMPO-catalyzed aerobic oxidation of primary alcohols to aldehydes with ambient air
Catalyst in Diels-Alder and Ullmann reactions, intramolecular aromatic annulations, ring expansions in steroids, asymmetric aziridination of alkenes, substitution of allylic halides and mesylates, the Kharasch-Sosnovsky reaction.
신호어
Danger
유해 및 위험 성명서
Hazard Classifications
Skin Corr. 1B
Storage Class Code
8A - Combustible corrosive hazardous materials
WGK
WGK 3
Flash Point (°F)
Not applicable
Flash Point (°C)
Not applicable
개인 보호 장비
Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges
이미 열람한 고객
![1,4-Diazabicyclo[2.2.2]octane bis(sulfur dioxide) adduct ≥95% (sulfur, elemental analysis)](/deepweb/assets/sigmaaldrich/product/structures/158/739/a9df497b-883d-40f1-ac45-bf699dcee9f9/640/a9df497b-883d-40f1-ac45-bf699dcee9f9.png)
Paryzek, Z.; Martynow, J.
Journal of the Chemical Society. Perkin Transactions 1, 599-599 (1990)
Kevin M Gillespie et al.
The Journal of organic chemistry, 67(10), 3450-3458 (2002-05-11)
Racemic 2,2'-diamino-6,6'-dimethylbiphenyl is resolved using simulated moving bed chromatography, and the absolute configuration of the enantiomers is confirmed via the X-ray crystal structure of a derivative. The diamine is condensed with a range of aldehydes to give bidentate aldimine proligands
Kerry E Murphy et al.
Organic letters, 7(7), 1255-1258 (2005-03-25)
[reaction: see text] Peptide-based chiral ligands, readily prepared from commercially available materials, are used to promote Cu-catalyzed asymmetric allylic alkylations of alpha,beta-unsaturated esters bearing a gamma-phosphate with various alkylzinc reagents. These transformations lead to the formation of alpha,alpha'-dialkyl-beta,gamma-unsaturated esters in
Le Bras, J.; Muzart, J.
Tetrahedron Letters, 43, 431-431 (2002)
Tobias Schneider et al.
Scientific reports, 9(1), 19991-19991 (2019-12-29)
Ubiquitylation is an eminent posttranslational modification referring to the covalent attachment of single ubiquitin molecules or polyubiquitin chains to a target protein dictating the fate of such labeled polypeptide chains. Here, we have biochemically produced artificially Lys11-, and Lys27-, and
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