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![9-Azabicyclo[3.3.1]nonane N-oxyl 95%](/deepweb/assets/sigmaaldrich/product/structures/287/155/e2f4a2e1-1d4e-4bed-9187-9e16d23cbbbf/640/e2f4a2e1-1d4e-4bed-9187-9e16d23cbbbf.png)
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설명
Freezing Point: 44.6°F
형태
liquid
반응 적합성
reagent type: oxidant
refractive index
n/D 1.357
density
0.796 at 25 °C
저장 온도
2-8°C
일반 설명
Stahl Aerobic Oxidation ABNO solution contains 1-methylimidazole (NMI), 2,2′-bipyridyl (bpy), and ABNO for the oxidation of primary and secondary alcohols.
애플리케이션
This convenience solution can be used in tandem with tetrakisacetonitrile copper(I) triflate (685038) for the oxidation of primary alcohols through aerobic conditions developed by the Stahl Research Group.
신호어
Danger
유해 및 위험 성명서
Hazard Classifications
Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Eye Dam. 1 - Flam. Liq. 2 - Repr. 2 - Skin Irrit. 2
Storage Class Code
3 - Flammable liquids
WGK
WGK 3
Flash Point (°F)
43.5 °F
Flash Point (°C)
6.38 °C
가장 최신 버전 중 하나를 선택하세요:
이미 열람한 고객
Efficient Aerobic Oxidation of Secondary Alcohols at Ambient Temperature with an ABNO/NOx Catalyst System
Lauber, MB, and Stahl, SS.
ACS Catalysis, 3 (11), 2612?2616-2612?2616 (2013)
Janelle E Steves et al.
Journal of the American Chemical Society, 135(42), 15742-15745 (2013-10-17)
Cu/TEMPO catalyst systems promote efficient aerobic oxidation of sterically unhindered primary alcohols and electronically activated substrates, but they show reduced reactivity with aliphatic and secondary alcohols. Here, we report a catalyst system, consisting of ((MeO)bpy)Cu(I)(OTf) and ABNO ((MeO)bpy = 4,4'-dimethoxy-2,2'-bipyridine;
Janelle E Steves et al.
The Journal of organic chemistry, 80(21), 11184-11188 (2015-10-13)
Two solutions, one consisting of bpy/TEMPO/NMI and the other bpy/ABNO/NMI (bpy =2,2'-bipyridyl; TEMPO = 2,2,6,6-tetramethylpiperidine N-oxyl, ABNO = 9-azabicyclo[3.3.1]nonane N-oxyl; NMI = N-methylimidazole), in acetonitrile are shown to have good long-term stability (≥1 year) under air at 5 °C. The
문서
Alcohol oxidation is one of the most frequently performed oxidation reactions in organic chemistry. The aldehyde and ketone products of alcohol oxidation are useful intermediates en route to complex molecules.
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