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core: ruthenium
reagent type: catalyst
reaction type: C-H Activation
환경친화적 대안 제품 특성
Catalysis
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mp
247.0-250.0 °C (dec.) (lit.)
환경친화적 대안 카테고리
, Aligned
SMILES string
Cl[Ru]Cl.Cl[Ru]Cl.CC(C)c1ccc(C)cc1.CC(C)c2ccc(C)cc2
InChI
1S/2C10H14.4ClH.2Ru/c2*1-8(2)10-6-4-9(3)5-7-10;;;;;;/h2*4-8H,1-3H3;4*1H;;/q;;;;;;2*+2/p-4
InChI key
LAXRNWSASWOFOT-UHFFFAOYSA-J
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일반 설명
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Dichloro(p-cymene)ruthenium(II) dimer is a saturated 18-electron complex used as a starting material for the synthesis of organometallic complexes.
Dichloro(p-cymene)ruthenium(II) dimer is a saturated 18-electron complex used as a starting material for the synthesis of organometallic complexes.
애플리케이션
Catalyst for greener amine synthesis by reduction of imines with PMHS or hydrogen-borrowing.
A Practical and Benign Synthesis of Primary Amines through Ruthenium-Catalyzed Reduction of Nitriles
Ruthenium-Catalyzed N-Alkylation of Amines and Sulfonamides Using Borrowing Hydrogen Methodology
A Practical and Benign Synthesis of Primary Amines through Ruthenium-Catalyzed Reduction of Nitriles
Ruthenium-Catalyzed N-Alkylation of Amines and Sulfonamides Using Borrowing Hydrogen Methodology
Cyclometalated ruthenium complexes with arylimines and nitrogen-containing heterocycles via C-H bond activation
신호어
Warning
유해 및 위험 성명서
Hazard Classifications
Eye Irrit. 2
Storage Class Code
11 - Combustible Solids
WGK
WGK 2
Flash Point (°F)
Not applicable
Flash Point (°C)
Not applicable
이미 열람한 고객
Chemistry (Weinheim an der Bergstrasse, Germany), 21(14), 5380-5386 (2015-02-18)
The Ru-catalysed C2-H arylation of indoles and pyrroles by using boronic acids under oxidative conditions is reported. This reaction can be applied to tryptophan derivatives and tolerates a wide range of functional groups on both coupling partners, including bromides and
Dalton transactions (Cambridge, England : 2003), 41(36), 10934-10937 (2012-08-15)
The reaction of [RuCl(2)(p-cymene)](2) with arylimines and 4 equiv. of KOAc in methanol at room temperature produces stable (N^C)-cyclometallated ruthenium(II) complexes via C-H bond activation/deprotonation. This method can be applied also to nitrogen-containing molecules: N-phenylpyrazole, 2-phenyl-2-oxazoline and benzo[h]quinoline. N-Phenyl-pyrazole, [RuCl(2)(p-cymene)](2)
문서
A Highly Efficient Hydrosilylation Catalyst, sigma-aldrich is pleased to offer [Cp*Ru(MeCN)3]PF6, as well as a number of other catalysts for hydrosilylation.
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