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Merck
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주요 문서

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667412

Sigma-Aldrich

Pentamethylcyclopentadienyltris (acetonitrile)ruthenium(II) hexafluorophosphate

동의어(들):

[RuCp*(MeCN)3]PF6

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모든 사진(2)

About This Item

실험식(Hill 표기법):
C16H24N3PRuF6
CAS Number:
99604-67-8
Molecular Weight:
504.42
MDL number:
MFCD08457650
UNSPSC 코드:
12161600
PubChem Substance ID:
24884913
NACRES:
NA.22

양식

solid

Quality Level

100

반응 적합성

core: ruthenium
reagent type: catalyst

저장 온도

2-8°C

SMILES string

[Ru+].CC#N.CC#N.CC#N.F[P-](F)(F)(F)(F)F.CC1C(C)=C(C)C(C)=C1C

InChI

1S/C10H16.3C2H3N.F6P.Ru/c1-6-7(2)9(4)10(5)8(6)3;3*1-2-3;1-7(2,3,4,5)6;/h6H,1-5H3;3*1H3;;/q;;;;-1;+1

InChI key

IYEMDYLFXFMECZ-UHFFFAOYSA-N

일반 설명

Pentamethylcyclopentadienyltris (acetonitrile)ruthenium(II) hexafluorophosphate is an organoruthenium compound. It is used as a homogeneous catalyst in organic synthesis. It enables the hydrosilylation of alkynes, cyclotrimerization of alkynes, cycloaddition reactions, and carbon-carbon or carbon-heteroatom bond-forming reactions.

애플리케이션

Hydrosilylation Catalysts
A versatile catalyst for hydrosilylation of alkynes providing α-vinylsilanes.
Reagent use as catalyst precursors for carbon-carbon or carbon-heteroatom bond forming reactions.

픽토그램

Exclamation mark
GHS07

신호어

Warning

유해 및 위험 성명서

H315,H319,H335

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

표적 기관

Respiratory system

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point (°F)

Not applicable

Flash Point (°C)

Not applicable

개인 보호 장비

dust mask type N95 (US), Eyeshields, Gloves

가장 최신 버전 중 하나를 선택하세요:

시험 성적서(COA)

Lot/Batch Number
MKCQ2935
MKCP9297
MKCP6392
MKCN9853
MKCN7825

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특정 버전이 필요한 경우 로트 번호나 배치 번호로 특정 인증서를 찾을 수 있습니다.

COA 검색

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문서 라이브러리에서 최근에 구매한 제품에 대한 문서를 찾아보세요.

문서 라이브러리 방문

Markovnikov alkyne hydrosilylation catalyzed by ruthenium complexes.
B M Trost et al.
Journal of the American Chemical Society, 123(50), 12726-12727 (2001-12-14)
Barry M Trost et al.
Journal of the American Chemical Society, 127(50), 17644-17655 (2005-12-15)
The complex [Cp*Ru(MeCN)3]PF6 is shown to catalyze the hydrosilylation of a wide range of alkynes. Terminal alkynes afford access to alpha-vinylsilane products with good regioselectivity. Deuterium labeling studies indicate a clean trans addition process is at work. The same complex

문서

Alkyne Hydrosilylation

Vinyl-metal reagents play a pivotal role in organic synthesis. Among the vinyl-metal reagents available, silicon-based reagents are of increasing importance. This is largely due to their low cost, minimal toxicity, ease of handling, and the simplicity of byproduct removal.

Hydrosilylation Catalyst

A Highly Efficient Hydrosilylation Catalyst, sigma-aldrich is pleased to offer [Cp*Ru(MeCN)3]PF6, as well as a number of other catalysts for hydrosilylation.

자사의 과학자팀은 생명 과학, 재료 과학, 화학 합성, 크로마토그래피, 분석 및 기타 많은 영역을 포함한 모든 과학 분야에 경험이 있습니다..

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