추천 제품
Quality Level
분석
97%
반응 적합성
core: ruthenium
reagent type: catalyst
reaction type: C-H Activation
SMILES string
Cl[Ru]Cl.c1ccc(cc1)P(c2ccccc2)c3ccccc3.c4ccc(cc4)P(c5ccccc5)c6ccccc6.c7ccc(cc7)P(c8ccccc8)c9ccccc9
InChI
1S/3C18H15P.2ClH.Ru/c3*1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;;;/h3*1-15H;2*1H;/q;;;;;+2/p-2
InChI key
WIWBLJMBLGWSIN-UHFFFAOYSA-L
유사한 제품을 찾으십니까? 방문 제품 비교 안내
애플리케이션
Tris(triphenylphosphine)ruthenium(II) dichloride or [RuCl2(PPh3)3] can be used as a catalyst to synthesize:
RuCl2(PPh3)3 can also be used as a catalyst in the cyclization, isomerization, reduction, oxidation, and cross-coupling reactions of a variety of organic products. Hydrogenation of nitro groups, imines, and ketones, as well as selective oxidation of alcohols are also possible in the presence of this catalyst.
- Functionalized alcohols by C-C cross-coupling reaction between different alcohols via sp3 C-H bond activation of primary alcohols in the presence of Lewis acid.
- Furan derivatives from allenyl sulfides via 1,4 migration of the sulfanyl group.
- 1,3-diphenylpropan-1-one by alkylation of acetophenone with benzyl alcohol via C-C bond formation.
- Vinyl chloride monomer by hydrochlorination reaction of acetylene.
RuCl2(PPh3)3 can also be used as a catalyst in the cyclization, isomerization, reduction, oxidation, and cross-coupling reactions of a variety of organic products. Hydrogenation of nitro groups, imines, and ketones, as well as selective oxidation of alcohols are also possible in the presence of this catalyst.
Storage Class Code
11 - Combustible Solids
WGK
WGK 3
Flash Point (°F)
Not applicable
Flash Point (°C)
Not applicable
개인 보호 장비
dust mask type N95 (US), Eyeshields, Gloves
이미 열람한 고객
Dichlorotris (triphenylphosphine) ruthenium (II) a
eEROS (Encyclopedia of Reagents for Organic Synthesis) (2001)
Cross-coupling reaction between alcohols through sp3 C-H activation catalyzed by a ruthenium/Lewis acid system.
Chemistry (Weinheim an der Bergstrasse, Germany), 14(33), 10201-10205 (2008-10-11)
Synthesis of vinyl chloride monomer over carbon-Supported tris-(triphenylphosphine) ruthenium dichloride catalysts
Catalysts, 8(7), 276-276 (2018)
Cross-Coupling Reaction between Alcohols through sp3 C-H Activation Catalyzed by a Ruthenium/Lewis Acid System
Chemistry?A European Journal , 14(33), 10201-10205 (2008)
ChemSusChem, 14(1), 339-343 (2020-10-21)
The sustainable, bio-based, platform chemical, 2,5-hexanedione [HD (1)], was efficiently converted to methylcyclopentadiene [MCPD (4)] through a three-step process consisting of intramolecular aldol condensation, catalytic chemoselective hydrogenation, and dehydration. Base-catalyzed aldol condensation of 1 resulted in the formation of 3-methyl-2-cyclopenten-1-one
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