추천 제품
양식
liquid
Quality Level
반응 적합성
reagent type: reductant
농도
1.0 M in THF
density
0.89 g/mL at 25 °C
SMILES string
[Li+].[H][B-](C(C)CC)(C(C)CC)C(C)CC
InChI
1S/C12H28B.Li/c1-7-10(4)13(11(5)8-2)12(6)9-3;/h10-13H,7-9H2,1-6H3;/q-1;+1
InChI key
ACJKNTZKEFMEAK-UHFFFAOYSA-N
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일반 설명
L-Selectride® is an air and water sensitive solution mainly used as a bulky stereoselective hydride reducing agent.
애플리케이션
L-Selectride® can be used as a reagent for:
- The stereoselective reduction of ketone to alcohol.
- The selective demethylation of tert alcohol.
L-Selectride® solution may be used in the O-demethylation and N-demethylation of opium alkaloids and their derivatives.
- Reducing agent
Reagent for:
- Enantioselective synthesis of a-amino acids via reduction of N-tert-butanesulfinyl ketimine esters
- Diastereoselective reduction reactions
- Hydride reduction of the Danishefsky pyranones
- Asymmetric reductive aldol reaction of enones with a-alkoxy aldehydes
- Synthesis of alkanols by carbonylation reactions
포장
법적 정보
Selectride is a registered trademark of Merck KGaA, Darmstadt, Germany
신호어
Danger
유해 및 위험 성명서
Hazard Classifications
Carc. 2 - Flam. Liq. 2 - Pyr. Liq. 1 - Skin Corr. 1B - STOT SE 3 - Water-react 1
표적 기관
Respiratory system
보충제 위험성
Storage Class Code
4.2 - Pyrophoric and self-heating hazardous materials
WGK
WGK 3
Flash Point (°F)
1.4 °F - closed cup
Flash Point (°C)
-17 °C - closed cup
개인 보호 장비
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
이미 열람한 고객
Li JJ, et al.
Modern Organic Synthesis in the Laboratory (2007)
Stereoselective synthesis of a novel pseudopeptide hapten for the generation of hydrolytic catalytic antibodies
Rodriguez AC, et al.
Tetrahedron Asymmetry, 15(12), 1847-1855 (2004)
L-Selectride as a General Reagent for the O-Demethylation and N-Decarbomethoxylation of Opium Alkaloids and Derivatives1.
Coop A, et al.
The Journal of Organic Chemistry, 63(13), 4392-4396 (1998)
Lithium Tri-sec-butylborohydride
Hubbard JL and Dake G.
e-EROS Encyclopedia of Reagents for Organic Synthesis. (2012)
A General and Simple Diastereoselective Reduction by L-Selectride: Efficient Synthesis of Protected (4S, 5S)-Dihydroxy Amides.
Yin B, et al.
Molecules (Basel), 15(4), 2771-2781 (2010)
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