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Key Documents

452882

Sigma-Aldrich

Sodium borohydride

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powder, ≥98.0%

동의어(들):

Sodium tetrahydridoborate

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About This Item

Linear Formula:
NaBH4
CAS Number:
Molecular Weight:
37.83
EC Number:
MDL number:
UNSPSC 코드:
12352302
PubChem Substance ID:
NACRES:
NA.22

Quality Level

분석

≥98.0%

형태

powder

포함

0.45-0.70% Magnesium carbonate as anticaking agent

반응 적합성

reagent type: reductant

환경친화적 대안 제품 특성

Design for Energy Efficiency
Learn more about the Principles of Green Chemistry.

sustainability

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불순물

≤100 ppm Silica

mp

>300 °C (dec.) (lit.)

양이온 미량물

Fe: ≤5 ppm

환경친화적 대안 카테고리

SMILES string

[BH4-].[Na+]

InChI

1S/BH4.Na/h1H4;/q-1;+1

InChI key

YOQDYZUWIQVZSF-UHFFFAOYSA-N

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일반 설명

Sodium borohydride (NaBH4) is the most commonly available borohydride, synthesized by reacting methylborate with sodium hydride in mineral oil. It is employed as a precursor for producing other metal borohydrides. Various approaches for qualitative and quantitative monitoring of sodium borohydride have been explained. The potential of NaBH4 to store as well as generate hydrogen for fuel cells has been investigated.
We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for energy efficiency. Find details here.

애플리케이션

Sodium borohydride can be used as a reducing agent:        
  • To prepare saturated alcohols by the reduction of conjugated aldehydes and ketones.        
  • Along with Raney nickel for the reduction of aromatic nitro compounds to arylamines.        
  • In the synthesis of secondary amines by reductive amination of ketones and aldehydes in the presence of an acid catalyst.       
  • In the synthesis of δ and γ lactones by the reduction of cyclic anhydrides.       
  • For the chemoselective reduction of N -protected amino acids and peptides to corresponding alcohols.

법적 정보

ASCENSUS SPECIALTIES LLC

신호어

Danger

유해 및 위험 성명서

Hazard Classifications

Acute Tox. 3 Oral - Eye Dam. 1 - Repr. 1B - Skin Corr. 1B - Water-react 1

보충제 위험성

Storage Class Code

4.3 - Hazardous materials which set free flammable gases upon contact with water

WGK

WGK 2

Flash Point (°F)

Not applicable

Flash Point (°C)

Not applicable

개인 보호 장비

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges


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Pectin Nanostructure Visualization by Atomic Force Microscopy.
Pose S, et al.
Bio-protocol, 5(19) (2015)
Analytical monitoring of sodium borohydride.
Sljukic B, et al.
Analytical Methods : Advancing Methods and Applications, 5(4), 829-839 (2013)
Reductive amination of aldehydes and ketones catalyzed by deep eutectic solvent using sodium borohydride as a reducing agent
Saberi D, et al.
Journal of Molecular Liquids, 196, 208-210 (2014)
Feng Geng et al.
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Rapid, efficient and selective reduction of aromatic nitro compounds with sodium borohydride and Raney nickel
Pogorelic I, et al.
J. Mol. Catal. A: Chem., 274(1-2), 202-207 (2007)

문서

An article about metal borohydrides as hydrogen storage materials

자사의 과학자팀은 생명 과학, 재료 과학, 화학 합성, 크로마토그래피, 분석 및 기타 많은 영역을 포함한 모든 과학 분야에 경험이 있습니다..

고객지원팀으로 연락바랍니다.