470260

4-Methoxyphenylmagnesium bromide solution

0.5 M in THF

• 동의어(들): (4-Methoxyphenyl)magnesium bromide, 4-Anisylmagnesium bromide, p-Methoxyphenylmagnesium bromide, Bromo(4-methoxyphenyl)magnesium
• Linear Formula: CH₃OC₆H₄MgBr
• CAS Number: 13139-86-1
• Molecular Weight: 211.34
• MDL number: MFCD00013515
• UNSPSC 코드: 12352103
• PubChem Substance ID: 24870649
• NACRES: NA.22

속성

• 반응 적합성: reaction type: Grignard Reaction
• 농도: 0.5 M in THF
• bp: 65-67 °C
• density: 0.955 g/mL at 25 °C
• SMILES string: COc1ccc([Mg]Br)cc1
• InChI: 1S/C7H7O.BrH.Mg/c1-8-7-5-3-2-4-6-7;;/h3-6H,1H3;1H;/q;;+1/p-1
• InChI key: JKXAZEXIOPFJSC-UHFFFAOYSA-M

설명

애플리케이션

4-Methoxyphenylmagnesium bromide is a general Grignard reagent that can be used:

• In the denickelation of porphyrins and to replace the metal center with magnesium.
• To synthesize a tubulin polymerization inhibitor, 2-Amino-3,4,5-trimethoxybenzophenone.
• In the total synthesis of (−)-centrolobine.

안전성 정보

• 픽토그램: GHS02,GHS08,GHS05,GHS07
• 신호어: Danger
• 유해 및 위험 성명서: H225,H302,H314,H335,H336,H351
• 예방조치 성명서: P210 - P280 - P301 + P312 - P303 + P361 + P353 - P304 + P340 + P310 - P305 + P351 + P338
• Hazard Classifications: Acute Tox. 4 Oral - Carc. 2 - Eye Dam. 1 - Flam. Liq. 2 - Skin Corr. 1B - STOT SE 3
• 표적 기관: Central nervous system, Respiratory system
• 보충제 위험성: EUH014,EUH018,EUH019
• Storage Class Code: 3 - Flammable liquids
• WGK: WGK 3
• Flash Point (°F): -4.0 °F
• Flash Point (°C): -20 °C