추천 제품
Quality Level
분석
97%
형태
liquid
포함
0.5% hydroquinone as stabilizer
refractive index
n20/D 1.518 (lit.)
bp
118-120 °C/13 mmHg (lit.)
density
1.069 g/mL at 25 °C (lit.)
SMILES string
O=CCOCc1ccccc1
InChI
1S/C9H10O2/c10-6-7-11-8-9-4-2-1-3-5-9/h1-6H,7-8H2
InChI key
NFNOAHXEQXMCGT-UHFFFAOYSA-N
일반 설명
Benzyloxyacetaldehyde is a non-natural aldehyde. It undergoes enantioselective Mukaiyama aldol reaction with silylketene acetal nucleophiles in the presence of C2-symmetric bis(oxazolinyl)pyridine Cu(II) complex (catalyst).
애플리케이션
Benzyloxyacetaldehyde may be used in the following syntheses:
- (3S,5S)-methyl 6-benzyloxy-3,5-dihydroxyhexanoate
- (S)-5-benzyloxy-4-hydroxypentan-2-one
- myxothiazols
Benzyloxyacetaldehyde may be used in the synthesis of 1-deoxy-L-xylulose, via antibody catalysis.
신호어
Warning
유해 및 위험 성명서
Hazard Classifications
Aquatic Chronic 2 - Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
표적 기관
Respiratory system
Storage Class Code
10 - Combustible liquids
WGK
WGK 3
Flash Point (°F)
235.4 °F - closed cup
Flash Point (°C)
113 °C - closed cup
개인 보호 장비
Eyeshields, Gloves, type ABEK (EN14387) respirator filter
이미 열람한 고객
Formal total syntheses of Myxothiazols by three different approaches starting from benzyloxyacetaldehyde.
Tetrahedron Letters, 41(13), 2087-2090 (2000)
A short enantioselective synthesis of 1-deoxy-L-xylulose by antibody catalysis.
Tetrahedron Letters, 40(8), 1437-1440 (1999)
Applied microbiology and biotechnology, 68(4), 489-497 (2005-02-24)
The glyA gene encoding a serine hydroxymethyl transferase (SHMT) with threonine aldolase activity was isolated from Streptococcus thermophilus YKA-184 chromosomal DNA. This aldolase is a pyridoxal 5'-phosphate-dependent enzyme that stereospecifically catalyzes the interconversion of L-threonine to glycine and acetaldehyde. The
C2-symmetric copper (II) complexes as chiral Lewis acids. Scope and mechanism of catalytic enantioselective aldol additions of enolsilanes to (benzyloxy) acetaldehyde.
Journal of the American Chemical Society, 121(4), 669-685 (1999)
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