추천 제품
Grade
reagent grade
Quality Level
vapor density
4.2 (vs air)
분석
97%
형태
liquid
autoignition temp.
554 °F
포함
≤1000 ppm propylene oxide as stabilizer
expl. lim.
7.3 %
refractive index
n20/D 1.469 (lit.)
bp
70-71 °C (lit.)
mp
−119 °C (lit.)
density
1.398 g/mL at 25 °C (lit.)
작용기
alkyl halide
bromo
저장 온도
2-8°C
SMILES string
BrCC=C
InChI
1S/C3H5Br/c1-2-3-4/h2H,1,3H2
InChI key
BHELZAPQIKSEDF-UHFFFAOYSA-N
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애플리케이션
Allyl bromide can be used:
- For the synthesis of stereodefined allylated arenes via Suzuki-type coupling reaction.
- In Barbier-type allylation reactions of aldehydes and ketones.{17]
- To synthesize a monomer, 1-1-(allyloxy)-4-nitrobenzene while synthesizing nanostructured molecularly imprinted polymer for selective tryptophan assay in biological and pharmaceutical samples.
신호어
Danger
유해 및 위험 성명서
Hazard Classifications
Acute Tox. 3 Inhalation - Acute Tox. 3 Oral - Aquatic Acute 1 - Carc. 1B - Eye Dam. 1 - Flam. Liq. 2 - Muta. 1B - Skin Corr. 1B
Storage Class Code
3 - Flammable liquids
WGK
WGK 3
Flash Point (°F)
30.2 °F - closed cup
Flash Point (°C)
-1 °C - closed cup
개인 보호 장비
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
이미 열람한 고객
A tryptophan assay based on the glassy carbon electrode modified with a nano-sized tryptophan-imprinted polymer and multi-walled carbon nanotubes
New. J. Chem., 41(11), 4493-4502 (2017)
Catalyst-Free Suzuki-Type Coupling of Allylic Bromides with Arylboronic Acids
European Journal of Organic Chemistry, 2012(2), 264-268 (2012)
Chemical communications (Cambridge, England), (26)(26), 3943-3945 (2009-08-08)
An efficient electrosynthesis of homoallylic alcohols from allylic bromides and aldehydes in aqueous ammonia is achieved in an undivided cell fitted with a pair of zinc electrodes.
Chemical communications (Cambridge, England), 46(41), 7801-7803 (2010-09-22)
Reaction of alkynylzirconates with allyl bromides afforded β-allyl-zirconacyclopentadienes with high selectivity in unique reaction site.
The Journal of organic chemistry, 75(18), 6308-6311 (2010-08-21)
The combination of an aldehyde, an allylic bromide, and tert-butanesulfinamide in the presence of indium metal and titanium tetraethoxide allows straightforward access to homoallylamine derivatives in high yields and stereoselectivities. Moreover, the synthetic utility of the enantioenriched homoallylamine derived from
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