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Merck
모든 사진(2)

주요 문서

236306

Sigma-Aldrich

Allyl chloride

ReagentPlus®, 99%

동의어(들):

3-Chloro-1-propene, Chlorallylene

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About This Item

Linear Formula:
CH2=CHCH2Cl
CAS Number:
Molecular Weight:
76.52
Beilstein:
635704
EC Number:
MDL number:
UNSPSC 코드:
12352100
PubChem Substance ID:
NACRES:
NA.22

vapor density

2.6 (vs air)

Quality Level

vapor pressure

20.58 psi ( 55 °C)
5.71 psi ( 20 °C)

제품 라인

ReagentPlus®

분석

99%

양식

liquid

expl. lim.

11.2 %

refractive index

n20/D 1.414 (lit.)

bp

44-46 °C (lit.)

mp

−130 °C (lit.)

solubility

alcohol: miscible(lit.)
chloroform: miscible(lit.)
diethyl ether: miscible(lit.)
petroleum ether: miscible(lit.)
water: slightly soluble(lit.)

density

0.939 g/mL at 25 °C (lit.)

작용기

alkyl halide
chloro

저장 온도

2-8°C

SMILES string

ClCC=C

InChI

1S/C3H5Cl/c1-2-3-4/h2H,1,3H2

InChI key

OSDWBNJEKMUWAV-UHFFFAOYSA-N

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일반 설명

Kinetcis of epoxidation of allyl chloride with hydrogen peroxide has been reported.

애플리케이션

Allyl chloride has been employed:
  • as precursor for generation of allyl radicals by laser flash photolysis at 193nm
  • in the synthesis of α,ω-difunctional chemical intermediates via the cross-metathesis reactions

법적 정보

ReagentPlus is a registered trademark of Merck KGaA, Darmstadt, Germany

신호어

Danger

Hazard Classifications

Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Aquatic Acute 1 - Carc. 2 - Eye Irrit. 2 - Flam. Liq. 2 - Muta. 2 - Skin Irrit. 2 - STOT RE 2 - STOT SE 3

표적 기관

Nervous system,Liver,Kidney, Respiratory system

Storage Class Code

3 - Flammable liquids

WGK

WGK 2

Flash Point (°F)

-25.6 °F

Flash Point (°C)

-32 °C

개인 보호 장비

Eyeshields, Faceshields, Gloves


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문서 라이브러리 방문

Cross-metathesis reactions of allyl chloride with fatty acid methyl esters: Efficient synthesis of a, ?-difunctional chemical intermediates from renewable raw materials.
Jacobs T, et al.
Applied Catalysis A: General, 353(1), 32-35 (2009)
Lars Seidel et al.
Molecules (Basel, Switzerland), 18(11), 13608-13622 (2013-11-07)
Photochemically driven reactions involving unsaturated radicals produce a thick global layer of organic haze on Titan, Saturn's largest moon. The allyl radical self-reaction is an example for this type of chemistry and was examined at room temperature from an experimental
Epoxidation of allyl chloride with hydrogen peroxide catalyzed by titanium silicalite 1.
Gao H, et al.
Applied Catalysis A: General, 138(1), 27-38 (1996)
Carbocycle synthesis through facile and efficient palladium-catalyzed allylative de-aromatization of naphthalene and phenanthrene allyl chlorides.
Shirong Lu et al.
Angewandte Chemie (International ed. in English), 47(23), 4366-4369 (2008-04-30)
Vikas Sikervar et al.
The Journal of organic chemistry, 77(11), 5132-5138 (2012-04-27)
A coupling strategy for the synthesis of 2,4-dimethyl-1α,25(OH)(2)D(3) is achieved which involves methylation of a pro-A ring vinyl sulfone and in situ traping of the allyl sulfonyl anion with a CD ring allyl chloride. TBAF-promoted 1,2-eliminative desulfonylation and concomitant silyl

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