추천 제품
Grade
reagent grade
Quality Level
vapor density
5.8 (vs air)
분석
98%
형태
liquid
불순물
≤0.5% p-bromotoluene
refractive index
n20/D 1.575 (lit.)
bp
198-199 °C (lit.)
mp
−3-−1 °C (lit.)
density
1.438 g/mL at 25 °C (lit.)
SMILES string
BrCc1ccccc1
InChI
1S/C7H7Br/c8-6-7-4-2-1-3-5-7/h1-5H,6H2
InChI key
AGEZXYOZHKGVCM-UHFFFAOYSA-N
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일반 설명
Benzyl bromide is an aromatic halide that is mainly used as a protecting agent for protecting hydroxy group of alcohols via O-benzylation reaction.
애플리케이션
Benzyl bromide has been used as an initiator in the synthesis of poly(styrene-b-methylmethacrylate) copolymers by atom transfer radical polymerization. It can undergo Menschutkin reaction with 1, 2-dimethylimidazole to form 3-benzyl-1, 2-dimethylimidazolium bromide.
신호어
Warning
유해 및 위험 성명서
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
표적 기관
Respiratory system
Storage Class Code
6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials
WGK
WGK 2
Flash Point (°F)
186.8 °F - closed cup
Flash Point (°C)
86 °C - closed cup
개인 보호 장비
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
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시험 성적서(COA)
Lot/Batch Number
이미 열람한 고객
A novel acid-catalyzed O-benzylating reagent with the smallest unit of imidate structure.
Yamada K
Organic Letters, 14(19), 5026-5029 (2012)
Yukiko Fujii et al.
Environmental pollution (Barking, Essex : 1987), 247, 312-318 (2019-01-28)
We investigated the profiles and levels of perfluoroalkyl carboxylic acid (PFCA) contamination in Pacific cod (Gadus macrocephalus) from the North Pacific Ocean. The mean concentrations of PFCAs containing 8 to 14 carbon atoms (C8-C14) in edible Pacific cod muscle ranged
Vanderlisa Rita Meleti et al.
Acta tropica, 202, 105248-105248 (2019-11-05)
This paper reports the synthesis of (±)-licarin A 1, a dihydrobenzofuran neolignan, resultant of an oxidative coupling reaction of isoeugenol and horseradish peroxidase (HRP) enzyme. Following, three semi-synthetic derivatives from this compound were obtained: benzylated (±)-licarin A 2, methylated (±)-licarin
Simon J Mountford et al.
Organic & biomolecular chemistry, 15(34), 7173-7180 (2017-08-16)
The first total synthesis of a polypeptin, PE2, as well as its solution structure is reported. Synthesis in optically pure form confirms the proposed stereochemistry of the polypeptins at the 3-position on the 3-hydroxy depsipeptide moiety. We have also determined
Wing-Yiu Yu et al.
Organic letters, 11(2), 469-472 (2008-12-23)
A Pd-catalyzed cross-coupling reaction of benzyl bromides with alpha-aryldiazoesters is described, and E-alpha,beta-diarylacrylates were obtained in good yields and excellent E-to-Z selectivity (>20:1).
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