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Merck
모든 사진(1)

문서

257443

Sigma-Aldrich

Fluoroacetonitrile

98%

동의어(들):

2-Fluoroacetonitrile, Fluoromethyl cyanide, Monofluoroacetonitrile

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모든 사진(1)

About This Item

Linear Formula:
FCH2CN
CAS Number:
503-20-8
Molecular Weight:
59.04
MDL number:
MFCD00009969
UNSPSC 코드:
12352100
PubChem Substance ID:
24855588
NACRES:
NA.22

분석

98%

형태

liquid

refractive index

n20/D 1.333 (lit.)

bp

79-80 °C (lit.)

density

1.061 g/mL at 25 °C (lit.)

SMILES string

FCC#N

InChI

1S/C2H2FN/c3-1-2-4/h1H2

InChI key

GNFVFPBRMLIKIM-UHFFFAOYSA-N

관련 카테고리

애플리케이션

Fluoroacetonitrile has been used in preparation of:
  • 2-fluoromethyl-4,4,6-trimethyl-1,3-oxazine
  • α-fluorinated acetophenone
  • 2-amino-2-fluoromethyl-3-pentenenitrile, a key intermediate in the synthesis of 2,5-diamino-2-fluoromethyl-3(E)-pentenoic acid

픽토그램

FlameSkull and crossbones
GHS02,GHS06

신호어

Danger

유해 및 위험 성명서

H225,H301 + H311 + H331,H315,H319,H335

Hazard Classifications

Acute Tox. 3 Dermal - Acute Tox. 3 Inhalation - Acute Tox. 3 Oral - Eye Irrit. 2 - Flam. Liq. 2 - Skin Irrit. 2 - STOT SE 3

표적 기관

Respiratory system

Storage Class Code

3 - Flammable liquids

WGK

WGK 3

Flash Point (°F)

6.8 °F - closed cup

Flash Point (°C)

-14 °C - closed cup

개인 보호 장비

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter

시험 성적서(COA)

제품의 로트/배치 번호를 입력하여 시험 성적서(COA)을 검색하십시오. 로트 및 배치 번호는 제품 라벨에 있는 ‘로트’ 또는 ‘배치’라는 용어 뒤에서 찾을 수 있습니다.

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문서 라이브러리 방문

Preparative flow techniques. 2. Grignard addition reaction on fluoroaceto-nitrile: Synthesis of 2-amino-2-fluoromethyl-3-pentenenitrile.
Gerhart F, et al.
Journal of Fluorine Chemistry, 50(2), 243-249 (1990)
2-Fluoromethyl-4, 4, 6-trimetiiyl-1, 3-oxasine as a new reagent for the preparation of a-fluoroaldehydes.
Patrick TB, et al.
Tetrahedron Letters, 31(2), 179-182 (1990)
Erum Raja et al.
Tetrahedron letters, 52(40), 5170-5172 (2012-03-03)
Fluoro-substituted aliphatic nitriles are shown to undergo the Houben-Hoesch reactions with arenes in CF(3)SO(3)H to give fluoro-substituted ketones in good yields. The fluorine substituents appear to enhance the reactivities of the nitriles (and the nitrilium ion intermediates) compared to similar
Santanu Mondal et al.
ACS chemical biology, 13(4), 1057-1065 (2018-03-09)
Protein arginine deiminases (PADs) play an important role in the pathogenesis of various diseases, including rheumatoid arthritis, multiple sclerosis, lupus, ulcerative colitis, and breast cancer. Therefore, the development of PAD inhibitors has drawn significant research interest in recent years. Herein

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