추천 제품
분석
98%
refractive index
n20/D 1.37 (lit.)
bp
75 °C (lit.)
density
1.054 g/mL at 25 °C (lit.)
작용기
fluoro
ketone
저장 온도
2-8°C
SMILES string
CC(=O)CF
InChI
1S/C3H5FO/c1-3(5)2-4/h2H2,1H3
InChI key
MSWVMWGCNZQPIA-UHFFFAOYSA-N
일반 설명
Aldolizations of fluoroacetone with aldehydes mediated by organocatalyst yield products with high enantioselectivities.
애플리케이션
Fluoroacetone has been used as a catalyst to study the kinetics of the ketone-catalysed decomposition of peroxymonosulfuric acid (Caro′s acid).
신호어
Danger
유해 및 위험 성명서
Hazard Classifications
Acute Tox. 2 Dermal - Acute Tox. 2 Inhalation - Acute Tox. 2 Oral - Flam. Liq. 2
Storage Class Code
3 - Flammable liquids
WGK
WGK 3
Flash Point (°F)
44.6 °F - closed cup
Flash Point (°C)
7 °C - closed cup
개인 보호 장비
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
이미 열람한 고객
Lange A, et al.
J. Chem. Soc. Perkin Trans. II, 7, 1343-1350 (1999)
Xiao-Hua Chen et al.
Chemistry (Weinheim an der Bergstrasse, Germany), 13(2), 689-701 (2006-10-03)
An organocatalyst prepared from (2R,3R)-diethyl 2-amino-3-hydroxysuccinate and L-proline exhibited high regio- and enantioselectivities for the direct aldol reactions of hydroxyacetone and fluoroacetone with aldehydes in aqueous media. It was found that water could be used to control the regioselectivity. The
Laura B Favero et al.
The journal of physical chemistry. A, 115(34), 9493-9497 (2011-03-17)
The rotational spectra of five isotopologues of the molecular adduct 1,1,1-trifluoroacetone-water have been assigned using pulsed-jet Fourier-transform microwave spectroscopy. All rotational transitions appear as doublets, due to the internal rotation of the methyl group. Analysis of the tunneling splittings allows
Y Shiratori et al.
Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy, 56A(9), 1693-1701 (2000-08-22)
The effects of water and heavy water on conformational equilibria of fluoroacetone have been investigated via Raman spectroscopy. Additional Raman bands have been observed in the C-F stretching and the C-C-C symmetric stretching regions for the aqueous solutions. Based on
Kimiyasu Isobe et al.
Applied microbiology and biotechnology, 102(3), 1307-1316 (2017-12-15)
The enzyme responsible for the enantioselective production of (S)-1,1,1-trifluoro-2-propanol ((S)-TFP) from 1,1,1-trifluoroacetone (TFA) has been identified in Ogataea polymorpha NBRC 0799. We purified two carbonyl reductases, OpCRD-A and OpCRD-B from this strain, and revealed their characteristics. Both enzymes were specific
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