435597

発煙硫酸

reagent grade, 20%, as free SO₃

• 別名: オレウム
• 化学式: H₂SO₄ · (SO₃)_x
• CAS番号: 8014-95-7
• 分子量: 98.08
• Beilstein: 2037554
• MDL番号: MFCD00137792
• UNSPSCコード: 12352106
• PubChem Substance ID: 329756351
• NACRES: NA.21

特性

• グレード: reagent grade
• 品質水準: 100
• 蒸気密度: 3 (vs air)
• 蒸気圧: 2 mmHg ( 25 °C)
• 形状: liquid
• 濃度: 20% (free SO₃)
• 密度: 1.925 g/mL at 25 °C (lit.)
• SMILES記法: O=S(=O)=O.OS(O)(=O)=O
• InChI: 1S/H2O4S.O3S/c1-5(2,3)4;1-4(2)3/h(H2,1,2,3,4);
• InChI Key: HIFJUMGIHIZEPX-UHFFFAOYSA-N

詳細

詳細

Fuming sulfuric acid is an inorganic acid, that can be produced by the addition of sulfur trioxide to concentrated sulfuric acid. It is commonly used as a sulfonating reagent in sulfonation reactions. When fuming sulfuric acid is employed as reaction medium, bromination takes place only in the pyridine nucleus of isomeric methylpyridines and 2,6-dimethylpyridine. It can also oxidize fullerene C₆₀ to form fullerene polymers.

アプリケーション

Fuming sulfuric acid may be used as a sulfonating agent for the synthesis of:

• sulfonated poly(1,4-phenylene sulfide)
• water-soluble polyphosphazene polyelectrolyte
• sulfated graphene

安全性情報

• ピクトグラム: GHS06,GHS05
• シグナルワード: Danger
• 危険有害性情報: H314,H330,H335
• 注意書き: P260 - P271 - P280 - P303 + P361 + P353 - P304 + P340 + P310 - P305 + P351 + P338
• 危険有害性の分類: Acute Tox. 2 Inhalation - Skin Corr. 1A - STOT SE 3
• ターゲットの組織: Respiratory system
• 補足的ハザード: EUH014
• 保管分類コード: 6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials
• WGK: WGK 1
• 引火点(°F): Not applicable
• 引火点(℃): Not applicable