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Merck

43861

Supelco

フラン

analytical standard

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About This Item

実験式(ヒル表記法):
C4H4O
CAS番号:
分子量:
68.07
Beilstein:
103221
EC Number:
MDL番号:
UNSPSCコード:
85151701
PubChem Substance ID:
NACRES:
NA.24

グレード

analytical standard

品質水準

蒸気密度

2.35 (vs air)

蒸気圧

1672 mmHg ( 55 °C)
31.66 psi ( 55 °C)
493 mmHg ( 20 °C)
9.22 psi ( 20 °C)

アッセイ

≥98.0% (GC)

シェルフライフ

limited shelf life, expiry date on the label

含みます

~0.025% 2,6-di-tert-4-methylphenol as stabilizer

expl. lim.

14.3 %

テクニック

HPLC: suitable
gas chromatography (GC): suitable

屈折率

n20/D 1.421 (lit.)
n20/D 1.421

bp

32 °C/758 mmHg (lit.)

密度

0.936 g/mL at 25 °C (lit.)

アプリケーション

cleaning products
cosmetics
environmental
food and beverages
personal care

フォーマット

neat

保管温度

2-8°C

SMILES記法

c1ccoc1

InChI

1S/C4H4O/c1-2-4-5-3-1/h1-4H

InChI Key

YLQBMQCUIZJEEH-UHFFFAOYSA-N

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詳細

Furan is a clear and colorless liquid, and a bimolecular heterocycle, which can be used to trap unstable intermediates containing highly reactive species, via Diels-Alder cycloaddition reactions.
Furan, a naturally occurring compound associated with the flavor of food, is found at very low levels in a variety of food products and beverages. It finds applications as a solvent for resins and lacquers as well as in the preparation of organic compounds, in pharmaceuticals, etc. Furan is also reportedly identified in heat treated food products, including cooked chicken, fish protein concentrate, caramel back, canned meat, bread, coffee, etc.

アプリケーション

Furan can undergo Diels-Alder [4+2] cycloaddition reaction with maleic anhydride to form the corresponding exo and endo furan-maleic anhydride adducts.
Furan may be used as an analytical reference standard for the quantification of the analyte in heat-processed foods using gas chromatography-mass spectrometry (GC-MS).
Refer to the product′s Certificate of Analysis for more information on a suitable instrument technique. Contact Technical Service for further support.

ピクトグラム

FlameHealth hazardExclamation mark

シグナルワード

Danger

危険有害性の分類

Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Aquatic Chronic 3 - Carc. 1B - Flam. Liq. 1 - Muta. 2 - Skin Irrit. 2 - STOT RE 2

補足的ハザード

保管分類コード

3 - Flammable liquids

WGK

WGK 3

引火点(°F)

-32.8 °F - closed cup

引火点(℃)

-36 °C - closed cup


適用法令

試験研究用途を考慮した関連法令を主に挙げております。化学物質以外については、一部の情報のみ提供しています。 製品を安全かつ合法的に使用することは、使用者の義務です。最新情報により修正される場合があります。WEBの反映には時間を要することがあるため、適宜SDSをご参照ください。

PRTR

第二種指定化学物質

消防法

第4類:引火性液体
特殊引火物
危険等級I

労働安全衛生法名称等を表示すべき危険物及び有害物

名称等を表示すべき危険物及び有害物

労働安全衛生法名称等を通知すべき危険物及び有害物

名称等を通知すべき危険物及び有害物

Jan Code

43861-1ML:
43861-BULK:
43861-VAR:


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試験成績書(COA)

Lot/Batch Number

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Slide 1 of 3

1 of 3

Synthetic applications of furan Diels-Alder chemistry
Kappe O.C, et al.
Tetrahedron, 53(42), 14179-14233 (1997)
Analysis of furan in heat-processed foods in China by automated headspace gas chromatography-mass spectrometry (HS-GC-MS)
Nie P-S, et al.
Food Control, 30(1), 62-68 (2013)
Carolin Neuwirth et al.
Molecular nutrition & food research, 56(9), 1363-1374 (2012-08-07)
Furan is a potent hepatotoxicant and liver carcinogen in rodents. However, short-term tests for genotoxicity of furan are inconclusive. The aim of this study was to assess the potential of furan to covalently bind to DNA, and to assess furan
C W Heppner et al.
Food additives and contaminants, 24 Suppl 1, 114-121 (2007-09-22)
Furan is an organic, volatile compound used in various chemical-manufacturing industries. Headspace gas chromatography is the analytical method of choice for obtaining reliable results on its occurrence. The presence of furan in some food items has been known since the
Rialet Pieters et al.
Environment international, 66, 71-78 (2014-02-18)
In South Africa, 26-50% of households use solid fuel for cooking food and heating houses. When used as fuel, wood and chlorinated waste are known sources of polychlorinated dibenzo-para-dioxins, polychlorinated dibenzofurans (PCDD/Fs), and polychlorinated biphenyls (PCBs). Here, we compare PCDD/F

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