ALD00618

(+)-PI Reagent

≥95%

• 別名: (2S,3aR,5S,7aR)-7a-methyl-2-((perfluorophenyl)thio)-5-(prop-1-en-2-yl)hexahydrobenzo[d][1,3,2]oxathiaphosphole 2-sulfide, Phosphorus Incorporation reagent
• 実験式（ヒル表記法）: C₁₆H₁₆F₅OPS₃
• CAS番号: 2269472-43-5
• 分子量: 446.46
• MDL番号: MFCD34470702
• UNSPSCコード: 12352005
• NACRES: NA.22

特性

• 品質水準: 100
• アッセイ: ≥95%
• フォーム: crystals
• mp: 119-124 °C
• SMILES記法: Fc1c(c(c(c(c1F)F)S[P]2(=S)S[C@H]3[C@](O2)(CC[C@@H](C3)C(=C)C)C)F)F
• InChI: 1S/C16H16F5OPS3/c1-7(2)8-4-5-16(3)9(6-8)25-23(24,22-16)26-15-13(20)11(18)10(17)12(19)14(15)21/h8-9H,1,4-6H2,2-3H3/t8-,9+,16+,23?/m0/s1
• InChI Key: CZCFCQOKUBIPHN-DWBMIXFYSA-N

詳細

アプリケーション

(+)-PI Reagent is an air- and moisture-tolerant, reagent developed in the Baran lab for stereospecific synthesis of chiral phosphines and methylphosphonate nucleotides. The enantiomer, (−)-PI Reagent, is also available.

Learn more about PI and PSI reagents

その他情報

Enantiodivergent formation of C-P bonds: synthesis of P-chiral phosphines and methyl-phosphonate oligonucleotides

安全性情報

• 保管分類コード: 11 - Combustible Solids
• WGK: WGK 3
• 引火点(°F): Not applicable
• 引火点(℃): Not applicable