931950

Sodium perchlorate

anhydrous, ≥99.9% trace metals basis

• 別名: Sodium Perchlorate, Hyperchloric acid sodium salt
• 実験式（ヒル表記法）: ClNaO₄
• CAS番号: 7601-89-0
• 分子量: 122.44
• MDL番号: MFCD00003480
• UNSPSCコード: 12352302
• NACRES: NA.23

特性

• グレード: anhydrous; battery grade
• 品質水準: 100
• アッセイ: ≥99.9% trace metals basis
• フォーム: powder
• 不純物: ≤1000 ppm (trace metals analysis)
• pH: 6.0-8.0 (25 °C, 5%, aq.sol.)
• mp: 482 °C
• 溶解性: H₂O: 209 g/dL at 15 °C
• 微量陰イオン: chloride (Cl^-): ≤30 ppm; sulfate (SO₄^2-): ≤20 ppm
• 微量陽イオン: Fe: ≤5 ppm; K: ≤500 ppm
• アプリケーション: battery manufacturing
• SMILES記法: [Na+].[Cl](=O)(=O)(=O)[O-]
• InChI: 1S/ClHO4.Na/c2-1(3,4)5;/h(H,2,3,4,5);/q;+1/p-1
• InChI Key: BAZAXWOYCMUHIX-UHFFFAOYSA-M

詳細

詳細

Anhydrous sodium perchlorate is a white crystalline solid. It is hygroscopic and absorbs water to form its monohydrate. Anhydrous sodium perchlorate is highly soluble in water, and soluble in a range of polar organic solvents such as methanol, ethanol, acetone, carbonates (including ethylene carbonate, dimethyl carbonate, propylene carbonate, and diethyl carbonate), and ethers (including dimethoxyethane, tetrahydrofuran, and triethylene glycol dimethyl ether). It is insoluble in benzene, chloroform, and toluene.

アプリケーション

The major application of anhydrous sodium perchlorate is as an electrolyte in sodium-ion batteries. It is popular because of its solubility in ethers and carbonates, its wide electrochemical stability window (e.g. from 0 to 5 V vs Na+/Na in propylene carbonate, triglyme, or diethylcarbonate)[1], and its compatibility with a wide range of materials. It has been used in batteries with hard-carbon anodes[2], mesoporous carbon anodes[3], sodium cobalt oxide cathodes (Na_xCoO₂)[4], sodium vanadium oxide cathodes (Na_xVO₂)[5], titanium dioxide cathodes[6], and emerging materials like high-entropy layered oxide cathodes[7].

包装

10 g in glass bottle
25 g in glass bottle

安全性情報

• ピクトグラム: GHS03,GHS08,GHS07
• シグナルワード: Danger
• 危険有害性情報: H271,H302,H319,H373
• 注意書き: P210 - P220 - P260 - P301 + P312 - P305 + P351 + P338 - P314
• 危険有害性の分類: Acute Tox. 4 Oral - Eye Irrit. 2 - Ox. Sol. 1 - STOT RE 2
• ターゲットの組織: Thyroid
• 保管分類コード: 5.1A - Strongly oxidizing hazardous materials
• WGK: WGK 1