922722

O-Pivaloylhydroxyamine triflic acid

• 別名: 2,2-dimethyl-, azanyl ester, 1,1,1-trifluoromethanesulfonate, PivONH₃OTF, Propanoic acid
• 実験式（ヒル表記法）: C₅H₁₁NO₂ · CHF₃O₃S
• CAS番号: 1293990-73-4
• 分子量: 267.22
• MDL番号: MFCD32701977
• UNSPSCコード: 12352106
• NACRES: NA.22

特性

• フォーム: solid
• 品質水準: 100
• 官能基: fluoro; triflate
• SMILES記法: FC(F)(F)[S](=O)(=O)[O-].[N+H3]OC(=O)C(C)(C)C
• InChI Key: AJUKGKFBUGZGSW-UHFFFAOYSA-M

詳細

アプリケーション

This hydroxylamine-based reagent enables the iron-catalyzed selective transformation of thiols to sulfinamides under mild conditions without the use of precious metal catalysts or additional oxidants. This reagent is shelf stable and facilitates the reaction in a single step and under mild conditions.

その他情報

Hydroxylamine-Derived Reagent as a Dual Oxidant and Amino Group Donor for the Iron Catalyzed Preparation of Unprotected Sulfinamides from Thiols

Synthesis of N-Alkyl Anilines from Arenes via Iron-Promoted Aromatic C–H Amination

安全性情報

• ピクトグラム: GHS05,GHS07
• シグナルワード: Danger
• 危険有害性情報: H302,H314,H335
• 注意書き: P260 - P271 - P280 - P301 + P312 - P303 + P361 + P353 - P305 + P351 + P338
• 危険有害性の分類: Acute Tox. 4 Oral - Eye Dam. 1 - Skin Corr. 1B - STOT SE 3
• ターゲットの組織: Respiratory system
• 保管分類コード: 8A - Combustible corrosive hazardous materials
• WGK: WGK 3
• 引火点(°F): Not applicable
• 引火点(℃): Not applicable