911828

PhPAd-DalPhos Ni(o-tolyl)Cl

≥95%

• 別名: (SP-4-3)-Chloro[8-[2-(diphenylphosphino-κP)phenyl]-1,3,5,7-tetramethyl-2,4,6-trioxa-8-phosphatricyclo[3.3.1.13,7]decane-κP8](2-methylphenyl)nickel
• 実験式（ヒル表記法）: C₃₅H₃₇ClNiO₃P₂
• CAS番号: 2290490-29-6
• 分子量: 661.76
• MDL番号: MFCD34166230
• UNSPSCコード: 12161600
• NACRES: NA.22

特性

• アッセイ: ≥95%
• フォーム: powder
• 反応適合性: reagent type: catalyst; reaction type: Cross Couplings
• mp: 235-248 °C
• SMILES記法: Cl[Ni]1(P(C(C2)(O3)C)(C4=CC=CC=C4P(C5=CC=CC=C5)1C6=CC=CC=C6)[C@@](C[C@]3(OC27C)C)(O7)C)C(C=CC=C8)=C8C

詳細

アプリケーション

PhPAd-DalPhos Ni(o-tolyl)Cl is an air stable precatalyst developed in the Stradiotto lab used for coupling of bulky primary amines with arenes.

その他情報

Technology Spotlight: DalPhos ligands

PhPAd-DalPhos: Ligand-Enabled, Nickel-Catalyzed Cross-Coupling of (Hetero)aryl Electrophiles with Bulky Primary Alkylamines

安全性情報

• ピクトグラム: GHS08,GHS07,GHS09
• シグナルワード: Danger
• 危険有害性情報: H302 + H332,H334,H341,H351,H361f,H372,H410
• 注意書き: P202 - P260 - P264 - P273 - P301 + P312 - P308 + P313
• 危険有害性の分類: Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Carc. 2 - Muta. 2 - Repr. 2 - Resp. Sens. 1 - STOT RE 1
• 保管分類コード: 6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects
• WGK: WGK 3
• 引火点(°F): Not applicable
• 引火点(℃): Not applicable