809330

Fe/ppm Pd for nitro group reductions

• MDL番号: MFCD00011005
• UNSPSCコード: 12161600
• NACRES: NA.22

特性

• 形状: solid
• 品質水準: 100
• 組成: FeCl₂ (372870), 23.3-27.4 wt. % ; MgCl₂ (M8266), 15.3-18.8 wt. % ; Pd (203939), <0.3 wt. % ; THF (186562), 53.5-61.6 wt. %
• 反応適合性: core: iron; reagent type: catalyst
• 保管温度: 2-8°C

詳細

アプリケーション

When these nanoparticles (NPs) are used along with PEG-containing designer surfactants such as TPGS-750-M, a facile reduction of nitro compounds can be effected in water at room temperature. The transformation is highly chemoselective and tolerates a large variety of functional groups.

注意

Handle under nitrogen and store under argon in refrigerator.

その他情報

Safe and Selective Nitro Group Reductions Catalyzed by Sustainable and Recyclable Fe/ppm Pd Nanoparticles in Water at Room Temperature

Watch Professor Lipshutz talk about Fe/ppm Pd in this webinar:
From milligrams to kilograms: synthetic chemistry following nature′s lead

安全性情報

• ピクトグラム: GHS02,GHS08,GHS05,GHS07
• シグナルワード: Danger
• 危険有害性情報: H225,H290,H302,H318,H335,H351
• 注意書き: P201 - P210 - P233 - P261 - P280 - P305 + P351 + P338 + P310
• 危険有害性の分類: Acute Tox. 4 Oral - Carc. 2 - Eye Dam. 1 - Flam. Liq. 2 - Met. Corr. 1 - STOT SE 3
• ターゲットの組織: Respiratory system
• 補足的ハザード: EUH018,EUH019
• 保管分類コード: 3 - Flammable liquids
• WGK: WGK 2
• 引火点(°F): 1.4 °F
• 引火点(℃): -17 °C