562076

3,5-Dimethylphenylmagnesium bromide solution

0.5 M in THF

• 化学式: (CH₃)₂C₆H₃MgBr
• CAS番号: 34696-73-6
• 分子量: 209.37
• MDL番号: MFCD01311497
• UNSPSCコード: 12352103
• PubChem Substance ID: 24880004
• NACRES: NA.22

特性

• 反応適合性: reaction type: Grignard Reaction
• 品質水準: 100
• 濃度: 0.5 M in THF
• bp: 65 °C
• 密度: 0.950 g/mL at 25 °C
• 保管温度: 2-8°C
• SMILES記法: Cc1cc(C)cc([Mg]Br)c1
• InChI: 1S/C8H9.BrH.Mg/c1-7-4-3-5-8(2)6-7;;/h4-6H,1-2H3;1H;/q;;+1/p-1
• InChI Key: XPXQQJMQESWIKM-UHFFFAOYSA-M

詳細

アプリケーション

3,5-Dimethylphenylmagnesium bromide solution can be used:

• As a starting material for the synthesis of diarylborinic acids, which on Suzuki coupling with vinyl triflate yield penultimate methyl ester.
• To prepare 3,5-dimethyl-p-terphenyl by reacting with biphenylsulfonate in the presence of dppfNiCl₂ catalyst.

法的情報

Rieke^® Metals, Inc.の製品です。

安全性情報

• ピクトグラム: GHS02,GHS07,GHS08
• シグナルワード: Danger
• 危険有害性情報: H225 - H302 - H319 - H335 - H351
• 注意書き: P210 - P280 - P301 + P312 + P330 - P305 + P351 + P338 - P370 + P378 - P403 + P235
• 危険有害性の分類: Acute Tox. 4 Oral - Carc. 2 - Eye Irrit. 2 - Flam. Liq. 2 - STOT SE 3
• ターゲットの組織: Respiratory system
• 補足的ハザード: EUH019
• 保管分類コード: 3 - Flammable liquids
• WGK: WGK 3
• 引火点(°F): -0.0 °F - closed cup
• 引火点(℃): -17.78 °C - closed cup