523216

メタクリロイルクロリド

97%, contains monomethyl ether hydroquinone as stabilizer

• 別名: α-Methylacryloyl chloride, 2-Methyl-2-propenoyl chloride, 2-Methylacryloyl chloride, 2-Methylpropenoic acid chloride, Methacrylic acid chloride, Methacrylic chloride
• 化学式: CH₂=C(CH₃)COCl
• CAS番号: 920-46-7
• 分子量: 104.53
• Beilstein: 878175
• EC Number: 213-058-9
• MDL番号: MFCD00000716
• UNSPSCコード: 12162002
• PubChem Substance ID: 24874306
• NACRES: NA.23

特性

• 品質水準: 200
• アッセイ: 97%
• 含みます: monomethyl ether hydroquinone as stabilizer
• 屈折率: n20/D 1.442 (lit.)
• bp: 95-96 °C (lit.)
• 密度: 1.07 g/mL at 25 °C (lit.)
• 保管温度: −20°C
• SMILES記法: CC(=C)C(Cl)=O
• InChI: 1S/C4H5ClO/c1-3(2)4(5)6/h1H2,2H3
• InChI Key: VHRYZQNGTZXDNX-UHFFFAOYSA-N

詳細

詳細

Methacryloyl chloride is the clear to slightly colored acid chloride of methacrylic acid. Monomethyl ether hydroquinone is added as a stabilizer to prevent auto polymerization. Reaction with diisopropyl ether in presence of metal salts is rigorous.

アプリケーション

Methacryloyl chloride is used in the manufacture of polymers:

• Monomer 2-methacrylamido-caprolactam was prepared by reacting methacryloyl chloride with racemic a-amino-e-caprolactam.
• Functional monomer was prepared by reacting methacryloyl chloride and L-histidine.
• A series of amide monomers were synthesized by amidation of methacryloyl chloride with amines and grafted onto commercial poly(ether sulfone) (PES) membranes using irradiation from atmospheric pressure plasma (APP).
• Reaction of methacryloyl chloride with the hydroxyl groups on the surfaces of HEMA/NVP microspheres was performed, leading to the introduction of polymerisable double bonds onto the surfaces of microspheres.
• Star-shaped poly(d,l-lactide) oligomers with 2, 3 and 6 arms were synthesised, end-functionalised with methacryloyl chloride and photo-crosslinked in the presence of ethyl lactate as a non-reactive diluent.

安全性情報

• ピクトグラム: GHS02,GHS06,GHS05
• シグナルワード: Danger
• 危険有害性情報: H225,H302,H314,H317,H330,H412
• 注意書き: P210 - P273 - P280 - P303 + P361 + P353 - P304 + P340 + P310 - P305 + P351 + P338
• 危険有害性の分類: Acute Tox. 1 Inhalation - Acute Tox. 4 Oral - Aquatic Chronic 3 - Eye Dam. 1 - Flam. Liq. 2 - Skin Corr. 1B - Skin Sens. 1
• 保管分類コード: 3 - Flammable liquids
• WGK: WGK 2
• 引火点(°F): 55.0 °F - closed cup
• 引火点(℃): 12.8 °C - closed cup
• 個人用保護具 (PPE): Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter