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蒸気圧
1 mmHg ( 70 °C)
アッセイ
99%
精製方法
sublimation
bp
236-238 °C (lit.)
mp
96-101 °C (lit.)
密度
0.908 g/mL at 25 °C (lit.)
SMILES記法
CC(C)(C)c1ccc(O)cc1
InChI
1S/C10H14O/c1-10(2,3)8-4-6-9(11)7-5-8/h4-7,11H,1-3H3
InChI Key
QHPQWRBYOIRBIT-UHFFFAOYSA-N
遺伝子情報
mouse ... Esr1(13982)
rat ... Ar(24208)
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詳細
4-tert-Butylphenol (t-BP, 4-TBP, p-tert-butylphenol, PTBP) is an alkyl phenol. It is an aquatic pollutant and an endocrine disrupting chemical (EDC). Exposure to 4-TBP is reported to be one of the factors causing vitiligo. Its genotoxic potential has been studied by in vivo micronucleus tests in a category approach. The degradation of t-BP in water using UV/micro-aeration process has been investigated. Methods for its determination in water and cereal samples have been reported. The kinetics of chlorination reaction of 4-tert-butylphenol in aqua has been studied. The hydrogenation of PTBP to form cis-4-tert-butylcyclohexanol (PTBCH) with high selectivity in the presence of supported rhodium catalyst has been reported. The effect of UV and combined MW–UV irradiation on 4-TBP transformation has been studied.
アプリケーション
4-tert-Butylphenol may be used as a sole carbon source for Sphingobium fuliginis strains isolated from rhizosphere sediment of the reed Phragmites australis. It may be used as a precursor to synthesize 4-fluorophenols.
シグナルワード
Danger
危険有害性情報
危険有害性の分類
Aquatic Chronic 1 - Eye Dam. 1 - Repr. 2 - Skin Irrit. 2
保管分類コード
11 - Combustible Solids
WGK
WGK 3
引火点(°F)
235.4 °F - closed cup
引火点(℃)
113 °C - closed cup
個人用保護具 (PPE)
dust mask type N95 (US), Eyeshields, Gloves
適用法令
試験研究用途を考慮した関連法令を主に挙げております。化学物質以外については、一部の情報のみ提供しています。 製品を安全かつ合法的に使用することは、使用者の義務です。最新情報により修正される場合があります。WEBの反映には時間を要することがあるため、適宜SDSをご参照ください。
PRTR
第2種指定化学物質
労働安全衛生法名称等を表示すべき危険物及び有害物
名称等を表示すべき危険物及び有害物
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名称等を通知すべき危険物及び有害物
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Stereoselective hydrogenation of p-tert-butylphenol over supported rhodium catalyst.
Yadav GD and Goel PK.
J. Mol. Catal. A: Chem., 184(1), 281-288 (2002)
Stereoselective cascade hydrogenation of 4-tert-butylphenol and p-cresol over Zr-zeolite beta- supported rhodium.
Nie Y, et al.
J. Catal., 246(1), 223-231 (2007)
Microwave photochemistry III: Photochemistry of 4-tert-butylphenol.
Cirkva V, et al.
Journal of Photochemistry and Photobiology A: Chemistry, 174(1), 38-44 (2005)
Synthesis of 4-fluorophenols from 4-tert-butylphenols and fluoride sources under oxidative conditions.
Bienvenu A, et al.
Collection of Czechoslovak Chemical Communications, 67(10), 1467-1478 (2002)
Sonnich Meier et al.
Comparative biochemistry and physiology. Toxicology & pharmacology : CBP, 145(3), 420-430 (2007-03-09)
Offshore oil production releases large amounts of lipophilic compounds in produced water into the ocean. In 2004, 143 million m(3) produced water, containing approximately 13 tons of long-chain (>C(4)) alkylphenols (AP), was discharged from installations in the Norwegian sector of
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