347191

meso-2,5-ジブロモアジピン酸ジエチル

98%

• 化学式: [-CH₂CH(Br)CO₂C₂H₅]₂
• CAS番号: 869-10-3
• 分子量: 360.04
• MDL番号: MFCD00075379
• UNSPSCコード: 12352100
• PubChem Substance ID: 24861319
• NACRES: NA.22

特性

• 品質水準: 100
• アッセイ: 98%
• mp: 65-67 °C (lit.)
• 官能基: bromo; ester
• SMILES記法: CCOC(=O)[C@@H](Br)CC[C@@H](Br)C(=O)OCC
• InChI: 1S/C10H16Br2O4/c1-3-15-9(13)7(11)5-6-8(12)10(14)16-4-2/h7-8H,3-6H2,1-2H3/t7-,8+
• InChI Key: UBCNJHBDCUBIPB-OCAPTIKFSA-N

詳細

詳細

Diethyl meso-2,5-dibromoadipate reacts with N-methylallylamine in the presence of potassium carbonate to yield two diastereomers of diethyl 2-allyl-N-methylpyrrolidine-2,5-dicarboxylate.

アプリケーション

Diethyl meso-2,5-dibromoadipate may be employed as difunctional initiator during n-butyl acrylate (n-BuA) polymerization, leading to α,ω-bromo-poly(n-BuA) having narrow molecular weight distribution. It was also used:

• as bifunctional atom transfer radical polymerization (ATRP) initiator
• as initiator during the solution polymerization of octadecyl ester ether dimer by ATRP
• in the synthesis of diethyl 2,5-diazidoadipate

安全性情報

• ピクトグラム: GHS05,GHS07
• シグナルワード: Danger
• 危険有害性情報: H314,H335
• 注意書き: P260 - P271 - P280 - P303 + P361 + P353 - P304 + P340 + P310 - P305 + P351 + P338
• 危険有害性の分類: Eye Dam. 1 - Skin Corr. 1B - STOT SE 3
• ターゲットの組織: Respiratory system
• 保管分類コード: 8A - Combustible corrosive hazardous materials
• WGK: WGK 3
• 引火点(°F): Not applicable
• 引火点(℃): Not applicable
• 個人用保護具 (PPE): Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges