333670

Tris(trimethylsilyl)phosphine

95%

• 別名: トリス(トリメチルシリル)ホスファン
• 化学式: [(CH₃)₃Si]₃P
• CAS番号: 15573-38-3
• 分子量: 250.54
• MDL番号: MFCD00015487
• UNSPSCコード: 12161700
• PubChem Substance ID: 24860167
• NACRES: NA.22

特性

• 品質水準: 100
• アッセイ: 95%
• フォーム: liquid
• 反応適合性: reaction type: Buchwald-Hartwig Cross Coupling Reaction; reaction type: Heck Reaction; reaction type: Hiyama Coupling; reaction type: Negishi Coupling; reaction type: Sonogashira Coupling; reaction type: Stille Coupling; reaction type: Suzuki-Miyaura Coupling; reagent type: ligand
• 屈折率: n20/D 1.502 (lit.)
• bp: 243-244 °C (lit.)
• 密度: 0.863 g/mL at 25 °C (lit.)
• 官能基: phosphine
• 保管温度: 2-8°C
• SMILES記法: C[Si](C)(C)P([Si](C)(C)C)[Si](C)(C)C
• InChI: 1S/C9H27PSi3/c1-11(2,3)10(12(4,5)6)13(7,8)9/h1-9H3
• InChI Key: OUMZKMRZMVDEOF-UHFFFAOYSA-N

詳細

アプリケーション

Tris(trimethylsilyl)phosphine (P(TMS)₃) can be used as a precursor for the syntheses of:

• Indium phosphide (InP) and indium gallium phosphide (InGaP) nanocrystals, type III-V semiconductors.
• Chiral TMS-phospholane which can be further used to synthesize various bisphospholane ligands for asymmetric catalysis.

安全性情報

• ピクトグラム: GHS02,GHS07
• シグナルワード: Danger
• 危険有害性情報: H250,H261,H315,H319,H335
• 注意書き: P210 - P222 - P231 + P232 - P302 + P352 - P305 + P351 + P338 - P370 + P378
• 危険有害性の分類: Eye Irrit. 2 - Pyr. Liq. 1 - Skin Irrit. 2 - STOT SE 3 - Water-react 2
• ターゲットの組織: Respiratory system
• 保管分類コード: 4.2 - Pyrophoric and self-heating hazardous materials
• WGK: WGK 3
• 引火点(°F): Not applicable
• 引火点(℃): Not applicable
• 個人用保護具 (PPE): Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter