276286

(1R)-(−)-Camphorquinone

99%

• 別名: 2,3-ボルナンジオン
• 実験式（ヒル表記法）: C₁₀H₁₄O₂
• CAS番号: 10334-26-6
• 分子量: 166.22
• Beilstein: 2327696
• MDL番号: MFCD00082863
• UNSPSCコード: 12352115
• PubChem Substance ID: 24856697
• NACRES: NA.22

特性

• 品質水準: 100
• アッセイ: 99%
• 光学活性: [α]20/D −101°, c = 2 in toluene
• mp: 200-203 °C (lit.)
• 官能基: ketone
• SMILES記法: CC1(C)[C@@H]2CC[C@@]1(C)C(=O)C2=O
• InChI: 1S/C10H14O2/c1-9(2)6-4-5-10(9,3)8(12)7(6)11/h6H,4-5H2,1-3H3/t6-,10+/m1/s1
• InChI Key: VNQXSTWCDUXYEZ-LDWIPMOCSA-N

詳細

アプリケーション

(1R)-(−)-Camphorquinone can be used as a chiral starting material for the preparation of:

• α-Hydroxycamphors by selective reduction of keto groups using various vegetables.
• Camphor-1,2-diamine platinum(II) complexes for DNA interaction studies.
• Camphoric anhydride by unsensitized photo-oxidation in the presence of oxygen and polar solvents.
• Camphorquinone-based chiral homoallylic amine, which is reacted with aldehydes to produce homoallylic primary amines via imine formation followed by 2-azonia-Cope rearrangement.

安全性情報

• ピクトグラム: GHS08,GHS07
• シグナルワード: Danger
• 危険有害性情報: H302,H334
• 注意書き: P261 - P264 - P270 - P284 - P301 + P312 - P501
• 危険有害性の分類: Acute Tox. 4 Oral - Resp. Sens. 1
• 保管分類コード: 11 - Combustible Solids
• WGK: WGK 3
• 引火点(°F): Not applicable
• 引火点(℃): Not applicable
• 個人用保護具 (PPE): dust mask type N95 (US), Eyeshields, Faceshields, Gloves