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形狀
liquid
品質等級
品質
filtered through a 1 μm filter
濃度
~0.45 M in acetonitrile
技術
DNA synthesis: suitable
雜質
≤0.003% water
bp
84 °C (lit.)
mp
156-158 °C (lit.)
密度
0.798 g/mL at 20 °C
SMILES 字串
c1nnn[nH]1
InChI
1S/CH2N4/c1-2-4-5-3-1/h1H,(H,2,3,4,5)
InChI 密鑰
KJUGUADJHNHALS-UHFFFAOYSA-N
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一般說明
本品为约 0.45M 四唑乙腈溶液。四唑环在各种合成和工业生产过程中起重要的作用。
應用
四唑溶液可用于 DNA 合成。它可用作在原位 合成脱氧核苷亚磷酰胺的催化剂。可用于制备以下阴离子核苷酸脂质：
- 胸苷 3′-（1,2-二苯甲酰- 锡 -甘油-3-磷酸），diC 12 -3′-dT
- 胸苷 3′-（1,2-二肉豆蔻酰- 锡 -甘油-3-磷酸）diC 14 -3′-dT
- 胸苷-3′-（1,2-二棕榈酰- 锡 -甘油-3-磷酸）diC 16 -3′-dT
注意
室温下为饱和溶液；低于室温储存会产生沉淀。
其他說明
寡核苷酸亚磷酸三酯法合成（二烷基氨基）膦偶联用催化剂
訊號詞
Danger
危險分類
Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Eye Irrit. 2 - Flam. Liq. 2
儲存類別代碼
3 - Flammable liquids
水污染物質分類（WGK）
WGK 3
閃點（°F）
41.0 °F - closed cup
閃點（°C）
5 °C - closed cup
個人防護裝備
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
其他客户在看
Azidoazomethine-tetrazole isomerism in solution: A thermochemical study.
Cubero E, et al.
The Journal of Organic Chemistry, 63(7), 2354-2356 (1998)
A D Barone et al.
Nucleic acids research, 12(10), 4051-4061 (1984-05-25)
Deoxynucleoside phosphoramidites can be prepared in good yield from deoxynucleosides, bis- dialkylaminophosphines , and the corresponding dialkylamine hydrotetrazolide or tetrazole as catalysts. These phosphoramidites generated in situ lead to the direct synthesis of deoxyoligonucleotides on polymer supports.
Salim Khiati et al.
Bioconjugate chemistry, 20(9), 1765-1772 (2009-08-29)
A family of new anionic nucleotide based lipids featuring thymidine-3'-monophosphate as nucleotide and 1,2-diacyl-sn-glycerol as lipid moiety for in vitro delivery of nucleic acids is described. The nucleotide lipids were prepared in three steps starting from 1,2-diacyl-sn-glycerols and 2'-deoxythymidine-3'-phosphoramidite. Gel
J Nielsen et al.
Nucleic acids research, 14(18), 7391-7403 (1986-09-25)
Deoxyribonucleoside phosphoramidites are prepared in situ from 5'-O,N-protected deoxyribonucleosides and 2-cyanoethyl N,N,N',N'-tetraisopropylphosphorodiamidite with tetrazole as catalyst, and the solutions applied directly on an automatic solid-phase DNA synthesizer. Using LCAA-CPG support and a cycle time of 12.5 min, oligonucleotides of 16-25
Adina Morozan et al.
ChemSusChem, 5(4), 647-651 (2012-03-06)
High-performance oxygen reduction reaction (ORR) catalysts based on metal-free nitrogen-containing precursors and carbon nanotubes are reported. The investigated systems allow the evaluation of the effect of nitrogen-containing groups towards ORR and the results show that the catalysts are compatible with
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