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Merck

M50834

Sigma-Aldrich

1-甲基咪唑

greener alternative

ReagentPlus®, 99%

别名:

N-Methylimidazole

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About This Item

经验公式(希尔记法):
C4H6N2
CAS号:
分子量:
82.10
Beilstein:
105197
EC號碼:
MDL號碼:
分類程式碼代碼:
12352005
PubChem物質ID:

生物源

synthetic

品質等級

蒸汽壓力

0.4 mmHg ( 20 °C)

產品線

ReagentPlus®

化驗

99%

形狀

liquid

自燃溫度

977 °F

expl. lim.

15.7 %

環保替代產品特色

Catalysis
Learn more about the Principles of Green Chemistry.

折射率

n20/D 1.495 (lit.)

bp

198 °C (lit.)

mp

−6 °C (lit.)

溶解度

water: soluble

密度

1.03 g/mL at 25 °C (lit.)

環保替代類別

SMILES 字串

Cn1ccnc1

InChI

1S/C4H6N2/c1-6-3-2-5-4-6/h2-4H,1H3

InChI 密鑰

MCTWTZJPVLRJOU-UHFFFAOYSA-N

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一般說明

我们致力于为您提供更环保的替代产品,以符合“绿色化学的12项原则”的一项或多项原则要求。该产品具有增强催化作用。点击此处,查看更多详情。

應用

用作在有氧条件下铜催化的、更环保的醇氧化过程中的助催化剂。

铜(I)/ABNO催化的有氧醇氧化:减轻Cu/TEMPO催化剂系统的空间和电子约束

法律資訊

ReagentPlus is a registered trademark of Merck KGaA, Darmstadt, Germany

象形圖

CorrosionSkull and crossbones

訊號詞

Danger

危險聲明

危險分類

Acute Tox. 3 Dermal - Acute Tox. 4 Oral - Skin Corr. 1B

儲存類別代碼

6.1A - Combustible, acute toxic Cat. 1 and 2 / very toxic hazardous materials

水污染物質分類(WGK)

WGK 2

閃點(°F)

197.6 °F - closed cup

閃點(°C)

92 °C - closed cup

個人防護裝備

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter


分析证书(COA)

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Pengfei Zhang et al.
Journal of chromatography. A, 1218(22), 3459-3465 (2011-04-19)
The development of mixed-mode stationary phase to achieve multiple separation capabilities in one column is very important for high performance liquid chromatography. In this paper, a new specific stationary phase based on grafting N-methylimidazolium to a monolithic silica column was
Bhaskar Sharma et al.
The journal of physical chemistry. A, 115(10), 1971-1984 (2011-02-22)
Quantum chemical [MP2(FULL)/6-311++G-(d,p)] calculations are done on the binding of hydrated Li(+), Na(+), K(+), Mg(2+), Cu(+), and Zn(2+) metal ions with biologically relevant heteroaromatics such as imidazole and methylimidazole. The computed interaction energies are found to be in good agreement
Zhan-Yong Wang et al.
The Journal of organic chemistry, 77(15), 6608-6614 (2012-07-19)
A well-defined NHC-Pd(II)-Im complex 1 was found to be an effective catalyst for the Suzuki-Miyaura coupling of aryl sulfonates including tosylates and phenylsulfonates with arylboronic acids, giving the desired coupling products in good to high yields. Acceptable yields can also
Wen-Xin Chen et al.
The Journal of organic chemistry, 77(20), 9236-9239 (2012-10-02)
We report herein that amides are excellent N-sources in the NHC-Pd(II)-Im complex 1 catalyzed amination of aryl chlorides. In the presence of KO(t)Bu, various aryl chlorides and amides can react smoothly to give the corresponding aminated products in moderate to
Ganesh N Pandian et al.
Bioorganic & medicinal chemistry, 20(8), 2656-2660 (2012-03-13)
Epigenetic modifications that govern the gene expression are often overlooked with the design of artificial genetic switches. N-Methylpyrrole-N-methylimidazole (PI) hairpin polyamides are programmable small DNA binding molecules that have been studied in the context of gene regulation. Recently, we synthesized

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