所有图片(1)
About This Item
线性分子式:
(C2H5)2NP(OCH2C6H5)2
CAS号:
分子量:
317.36
Beilstein:
4189915
MDL號碼:
分類程式碼代碼:
12352100
PubChem物質ID:
NACRES:
NA.22
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等級
technical grade
品質等級
蒸汽壓力
0.71 psi ( 55 °C)
化驗
85%
形狀
liquid
折射率
n20/D 1.545 (lit.)
密度
1.06 g/mL at 25 °C (lit.)
儲存溫度
2-8°C
SMILES 字串
CCN(CC)P(OCc1ccccc1)OCc2ccccc2
InChI
1S/C18H24NO2P/c1-3-19(4-2)22(20-15-17-11-7-5-8-12-17)21-16-18-13-9-6-10-14-18/h5-14H,3-4,15-16H2,1-2H3
InChI 密鑰
NLGUJOVLAXLSMX-UHFFFAOYSA-N
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一般說明
据报道，二苄基N,N-二乙基亚磷酰胺是受保护丝氨酸衍生物的高效的 1H-四唑催化′亚磷酸三酯′磷酸化的合适试剂。
應用
二苄基 N,N-二乙基亚磷酰胺可用于：
- 在糖基亚磷酸酯和磷酸酯的合成中作为亚磷酸化试剂。
- 醇的亚磷酸化
- 制备in the preparation of 6-二苄基磷酸-1,3,5-三-O-PMB--肌醇
訊號詞
Warning
危險分類
Eye Irrit. 2 - Flam. Liq. 3 - Skin Irrit. 2 - STOT SE 3
標靶器官
Respiratory system
儲存類別代碼
3 - Flammable liquids
水污染物質分類（WGK）
WGK 3
閃點（°F）
93.2 °F - closed cup
閃點（°C）
34 °C - closed cup
個人防護裝備
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
其他客户在看
Synthesis of Casein-Related Peptides and Phosphopeptides. V. The Efficient Global'Phosphite-Triester'Phosphorylation of Protected Serine Derivatives and Peptides by Using Dibenzyl or Di-t-butyl N, N-Diethylphosphoramidite.
Perich JW and Johns RB.
Australian Journal of Chemistry, 43(10), 1623-1632 (1990)
Synthesis of dibenzyl glycosyl phosphites using dibenzyl N, N-diethylphosphoramidite as phosphitylating reagent: an effective route to glycosyl phosphates, nucleotides, and glycosides.
Sim MM, et al.
Journal of the American Chemical Society, 115(6), 2260-2267 (1993)
Peter A Jordan et al.
Proceedings of the National Academy of Sciences of the United States of America, 107(48), 20620-20624 (2010-05-05)
Despite the ubiquitous use of phosphoramidite chemistry in the synthesis of biophosphates, catalytic asymmetric phosphoramidite transfer remains largely unexplored for phosphate ester synthesis. We have discovered that a tetrazole-functionalized peptide, in the presence of 10-Å molecular sieves, functions as an
Qiao Liao et al.
Acta pharmacologica Sinica, 40(10), 1314-1321 (2019-05-08)
Irisin, a myokine, is cleaved from the extracellular portion of fibronectin domain-containing 5 protein in skeletal muscle and myocardium and secreted into circulation as a hormone during exercise. Irisin has been found to exert protective effects against lung and heart injuries.
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