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Merck
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Key Documents

HX0080

Supelco

庚烷

greener alternative

别名:

n-Heptane, Heptane

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About This Item

线性分子式:
CH3(CH2)5CH3
CAS号:
分子量:
100.20
Beilstein:
1730763
MDL號碼:
分類程式碼代碼:
12191502
酶委員會索引編號:
205-563-8

蒸汽密度

3.5 (vs air)

品質等級

蒸汽壓力

40 mmHg ( 20 °C)
83 mmHg ( 37.7 °C)

化驗

≥99% n-heptane basis
≥99.9% (saturated C7 hydrocarbons)

形狀

liquid

自燃溫度

433 °F

expl. lim.

7 %

環保替代產品特色

Safer Solvents and Auxiliaries
Learn more about the Principles of Green Chemistry.

sustainability

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雜質

≤0.01% Water (H2O)

蒸發殘留物

≤5 ppm

顏色

APHA: ≤10

折射率

n20/D 1.387 (lit.)

bp

98 °C (lit.)

mp

−91 °C (lit.)

轉變溫度

flash point -4 °C

溶解度

0.05 g/L

密度

0.684 g/mL at 25 °C (lit.)

環保替代類別

運輸包裝

ambient

儲存溫度

room temp

SMILES 字串

CCCCCCC

InChI

1S/C7H16/c1-3-5-7-6-4-2/h3-7H2,1-2H3

InChI 密鑰

IMNFDUFMRHMDMM-UHFFFAOYSA-N

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一般說明

Heptane is a saturated, neutral aliphatic hydrocarbon derived from crude oil. It is commonly used as a laboratory solvent in organic synthesis due to its low reactivity with other molecules.
We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. Heptane is an environmentally preferable solvent compared to hexane and thus align with "Safer Solvents and Auxiliaries". Click here for more information.

應用

Heptane can be used in the following process:
  • As a solvent for the extraction of aromatic sulfur compounds.
  • A mixture of heptane/acetone solvent system used in the chromatographic purification of organic compounds.
  • Heptane/ionic liquid two-phase solvent system used to synthesize isoamyl acetate via esterification reaction using lipase as a catalyst.
  • As a weakly polar diluent to prepare mobile phase for thin-layer chromatography (TLC).
  • In the synthesis of SBA-15, heptane can be used as a pore swelling agent in combination with NH4F to control the particle morphology and pore size of SBA-15.

分析報告

Assay (n-heptane): 99.0% min
Assay (saturated C7 hydrocarbons): 99.9% min
Color (APHA): 10 max
Evaporation residue: 5ppm max
Form: Clear liquid
Infrared Spectrum: Conforms to standard
Water (H2O): 0.01% max

訊號詞

Danger

危險分類

Aquatic Acute 1 - Aquatic Chronic 1 - Asp. Tox. 1 - Flam. Liq. 2 - Skin Irrit. 2 - STOT SE 3

標靶器官

Central nervous system

儲存類別代碼

3 - Flammable liquids

水污染物質分類(WGK)

WGK 2

閃點(°F)

24.8 °F - closed cup

閃點(°C)

-4 °C - closed cup


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Acetone-heptane as a solvent system for combining chromatography on silica gel with solvent recycling
Drueckhammer DG, et al.
ACS sustainable chemistry & engineering, 1(1), 87-90 (2013)
Andrej Pohar et al.
Lab on a chip, 9(23), 3385-3390 (2009-11-12)
A continuously operated psi-shaped microreactor was used for lipase-catalyzed synthesis of isoamyl acetate in the 1-butyl-3-methylpyridinium dicyanamide/n-heptane two-phase system. The chosen solvent system with dissolved Candida antarctica lipase B, which was attached to the ionic liquid/n-heptane interfacial area due to

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