409405

氯三(三甲基甲硅烷基)硅烷

97%

• 别名: 1,1,1,3,3,3-Hexamethyl-2-(trimethylsilyl)-2-chlorotrisilane, 2-Chloro-1,1,1,3,3,3-hexamethyl-2-(trimethylsilyl)trisilane, Tris(trimethylsilyl)chlorosilane, Tris(trimethylsilyl)silyl chloride
• 线性分子式: [(CH₃)₃Si]₃SiCl
• CAS号: 5565-32-2
• 分子量: 283.11
• MDL號碼: MFCD01321222
• 分類程式碼代碼: 12352101
• PubChem物質ID: 24865643
• NACRES: NA.22

属性

• 品質等級: 100
• 化驗: 97%
• 形狀: solid
• mp: 50-52 °C (lit.)
• SMILES 字串: C[Si](C)(C)[Si](Cl)([Si](C)(C)C)[Si](C)(C)C
• InChI: 1S/C9H27ClSi4/c1-11(2,3)14(10,12(4,5)6)13(7,8)9/h1-9H3
• InChI 密鑰: HCOROOJWVHFMRJ-UHFFFAOYSA-N

说明

一般說明

Chlorotris(trimethylsilyl)silane is an organosilicon reagent, which is generally employed in the protection of alcohols. It is also used to prepare organometallic reagents, silyl enol ethers, and novel polymers/materials.

應用

Super Silyl Protecting Groups

Used for:

• Insertion into a P-P bond
• Diastereoselective aldol and cascade reactions
• Preparation of hypersilyl substituted monophosphines and diphosphines

安全信息

• 象形圖: GHS02,GHS07
• 訊號詞: Danger
• 危險聲明: H228,H261,H315,H319,H335
• 防範說明: P210 - P231 + P232 - P240 - P241 - P302 + P352 - P305 + P351 + P338
• 危險分類: Eye Irrit. 2 - Flam. Sol. 1 - Skin Irrit. 2 - STOT SE 3 - Water-react 3
• 標靶器官: Respiratory system
• 安全危害: EUH029
• 儲存類別代碼: 4.3 - Hazardous materials which set free flammable gases upon contact with water
• 水污染物質分類（WGK）: WGK 3
• 閃點（°F）: 87.8 °F - closed cup
• 閃點（°C）: 31 °C - closed cup
• 個人防護裝備: Eyeshields, Gloves, type P3 (EN 143) respirator cartridges