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Merck

348295

Sigma-Aldrich

4-吗啉碳酰氯

98%

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About This Item

经验公式(希尔记法):
C5H8ClNO2
CAS号:
分子量:
149.58
Beilstein:
116257
EC號碼:
MDL號碼:
分類程式碼代碼:
12352100
PubChem物質ID:
NACRES:
NA.22

品質等級

化驗

98%

形狀

liquid

折射率

n20/D 1.498 (lit.)

bp

137-138 °C/33 mmHg (lit.)

密度

1.282 g/mL at 25 °C (lit.)

官能基

chloro
ether

SMILES 字串

ClC(=O)N1CCOCC1

InChI

1S/C5H8ClNO2/c6-5(8)7-1-3-9-4-2-7/h1-4H2

InChI 密鑰

XMWFMEYDRNJSOO-UHFFFAOYSA-N

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一般說明

4-Morpholinecarbonyl chloride is a photographic intermediate. Rates of solvolysis of 4-morpholinecarbonyl chloride with N-alkyl group in aqueous binary solvents of acetone, ethanol, methanol, methanol-d, 2,2,2-trifluoroethanol, pure water and D2O has been determined. Preparation of 4-morpholinecarbonyl chloride has been reported.

應用

4-Morpholinecarbonyl chloride may be used in the preparation of a versatile fluorogenic label for biomolecular imaging. It may be used in the synthesis of:
  • morpholine-4-carboxylic acid [4-(2,4-dimethylphenyl)thiazol-2-yl]amide
  • morpholine-4-carboxylic acid [4-(2,4,6-trimethylphenyl)thiazol-2-yl]amide
  • 2-isopropyl-6-methylpyrimidin-4-yl morpholine-4-carboxylate

象形圖

Health hazardExclamation mark

訊號詞

Warning

危險聲明

危險分類

Carc. 2 - Eye Irrit. 2 - Skin Irrit. 2

安全危害

儲存類別代碼

10 - Combustible liquids

水污染物質分類(WGK)

WGK 3

閃點(°F)

235.4 °F - closed cup

閃點(°C)

113 °C - closed cup

個人防護裝備

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter


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分析证书(COA)

Lot/Batch Number

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访问文档库

Xiao-Long Qiu et al.
Journal of medicinal chemistry, 52(6), 1757-1767 (2009-02-27)
High expression in cancer 1 (Hec1) is an oncogene overly expressed in many human cancers. Small molecule inhibitor of Nek2/Hec1 (INH) targeting the Hec1 and its regulator, Nek2, in the mitotic pathway, was identified to inactivate Hec1/Nek2 function mediated by
Synthesis and antifungal activities of some novel pyrimidine derivatives.
Sun L, et al.
Molecules (Basel), 16(7), 5618-5628 (2011)
Correlation of the rates of solvolysis of 4-morpholinecarbonyl chloride using the extended Grunwald-Winstein equation.
Kim R, et al.
Bull. Korean Chem. Soc., 31(7), 1963-1963 (2010)
Luke D Lavis et al.
ACS chemical biology, 1(4), 252-260 (2006-12-14)
Traditional small-molecule fluorophores are always fluorescent. This attribute can obscure valuable information in biological experiments. Here, we report on a versatile "latent" fluorophore that overcomes this limitation. At the core of the latent fluorophore is a derivative of rhodamine in

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