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438081

Sigma-Aldrich

Acido fosforico

greener alternative

ACS reagent, ≥85 wt. % in H2O

Sinonimo/i:

Acido ortofosforico

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About This Item

Formula condensata:
H3PO4
Numero CAS:
Peso molecolare:
98.00
Beilstein:
1921286
Numero CE:
Numero MDL:
Codice UNSPSC:
12352106
ID PubChem:

Grado

ACS reagent

Livello qualitativo

Densità del vapore

3.4 (vs air)

Tensione di vapore

2.2 mmHg ( 20 °C)
5 mmHg ( 25 °C)

Saggio

≥85% (with NaOH, titration)

Forma fisica

liquid

Caratteristiche più verdi

Design for Energy Efficiency
Learn more about the Principles of Green Chemistry.

Concentrazione

≥85 wt. % in H2O

tecniche

NMR: suitable

Impurezze

Reducing substances, passes test
≤0.001% volatile acids (as CH3COOH)

Colore

APHA: ≤10

P. eboll.

158 °C (lit.)

Punto di fusione

~40 °C (lit.)

Densità

1.685 g/mL at 25 °C (lit.)

Anioni in tracce

chloride (Cl-): ≤3 ppm
nitrate (NO3-): ≤5 ppm
sulfate (SO42-): ≤0.003%

Cationi in tracce

As: ≤1 ppm
Ca: ≤0.002%
Fe: ≤0.003%
K: ≤0.005%
Mg: ≤0.02%
Mn: ≤0.5 ppm
Na: ≤0.025%
Sb: ≤0.002%
heavy metals: ≤0.001% (by ICP)

Categoria alternativa più verde

Stringa SMILE

OP(O)(O)=O

InChI

1S/H3O4P/c1-5(2,3)4/h(H3,1,2,3,4)
NBIIXXVUZAFLBC-UHFFFAOYSA-N

Informazioni sul gene

human ... SRC(6714)

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Descrizione generale

Phosphoric acid (H3PO4), also known as orthophosphoric acid, is an inorganic acid. It has a wide range of industrial applications such as an intermediate to produce animal feedstock, to prepare stock solutions for workup procedures and to treat the metal surfaces for better adhesion of paint and resin coatings. In the food industry it is used as a preservative, an acidulant and flavor enhancer.
We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for energy efficiency. Find details here.

Applicazioni

Phosphoric acid may be employed as standard for the determination of phosphorus-31 nuclear magnetic resonance (31P NMR) chemical shifts of the common phospholipids. It may be employed in the following studies:
  • As external standard for the analysis of lipid composition of human white matter by 31P NMR spectroscopy.
  • As external standard during the acid-labile phosphorylation of histone H4 by 31P NMR spectroscopy.
  • As reference standard to investigate the surface species present on silica/alumina-supported sodium phosphates by pre- and postreaction MAS31P-NMR and FTIR spectroscopies.
  • As catalyst in the vapor-phase Fries rearrangement of phenylacetate at 623K over a series of surface modified and unmodified ZSM-5.
  • As an eco-friendly reagent for the removal of protecting groups like tert-butyl carbamates, tert-butyl esters and tert-butyl ethers.

Altre note

L′acido fosforico concentrato è circa all′85% H3PO4 (acquoso).

Pittogrammi

CorrosionExclamation mark

Avvertenze

Danger

Indicazioni di pericolo

Classi di pericolo

Acute Tox. 4 Oral - Eye Dam. 1 - Met. Corr. 1 - Skin Corr. 1B

Codice della classe di stoccaggio

8A - Combustible, corrosive hazardous materials

Classe di pericolosità dell'acqua (WGK)

WGK 1

Punto d’infiammabilità (°F)

Not applicable

Punto d’infiammabilità (°C)

Not applicable


Certificati d'analisi (COA)

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Aqueous phosphoric acid as a mild reagent for deprotection of tert-butyl carbamates, esters, and ethers.
Li B, et al.
The Journal of Organic Chemistry, 71(24), 9045-9050 (2006)
A simple method of increasing the adhesion of acrylic filling materials to enamel surfaces.
Buonocore MG.
Journal of Dental Research, 34(6), 849-853 (1955)
Myers RL.
The 100 Most Important Chemical Compounds: A Reference Guide, 220-220 (2007)
FTIR and 31 P-NMR spectroscopic analyses of surface species in phosphate-catalyzed lactic acid conversion.
Gunter GC, et al.
J. Catal., 164(1), 207-219 (1996)
Internal versus external surface active sites in ZSM-5 zeolite: Part 1. Fries rearrangement catalyzed by modified and unmodified H3PO4/ZSM-5.
Ghiaci M, et al.
Applied Catalysis A: General, 298, 32-39 (2006)

Protocolli

This application illustrate how Rutin can be determined in skin cream samples using a monolithic Chromolith® HighResolution RP-18 endcapped column with UV detection.

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