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Documenti fondamentali

372145

Sigma-Aldrich

Trichloroethylene

anhydrous, contains 40 ppm diisopropylamine as stabilizer, ≥99%

Sinonimo/i:

TCE, Trichloroethene

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About This Item

Formula condensata:
ClCH=CCl2
Numero CAS:
Peso molecolare:
131.39
Beilstein:
1736782
Numero CE:
Numero MDL:
Codice UNSPSC:
12352101
ID PubChem:
NACRES:
NA.21
Grado:
anhydrous
Saggio:
≥99%
P. ebollizione:
86.7 °C (lit.)
Tensione di vapore:
61 mmHg ( 20 °C)

Grado

anhydrous

Livello qualitativo

Densità del vapore

4.5 (vs air)

Tensione di vapore

61 mmHg ( 20 °C)

Saggio

≥99%

Stato

liquid

Temp. autoaccensione

770 °F

contiene

40 ppm diisopropylamine as stabilizer

Impurezze

<0.002% water
<0.005% water (100 mL pkg)

Residuo dopo evaporazione

<0.0005%

Indice di rifrazione

n20/D 1.476 (lit.)

P. ebollizione

86.7 °C (lit.)

Punto di fusione

−84.8 °C (lit.)

Densità

1.463 g/mL at 25 °C (lit.)

Stringa SMILE

Cl\C=C(\Cl)Cl

InChI

1S/C2HCl3/c3-1-2(4)5/h1H
XSTXAVWGXDQKEL-UHFFFAOYSA-N

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Descrizione generale

Trichloroethylene (TCE) is a chlorinated ethylene compound commonly used as a dry cleaning and degreasing solvent. Without stabilizers, TCE is unstable and degrades easily in the presence of moisture air, light and heat, it can be minimized by adding diisopropylamine as a stabilizer. Various methods have been reported for its synthesis. One of them is by chlorinating ethylene dichloride. Since TCE is one of the most common industrial solvent it has led it to be a major contaminant found in the ground water. It has adverse effect on human health due to its potential toxicity and carcinogenicity. Its toxicity and carcinogenicity has been studied.
Many methods have been proposed for the mineralization of TCE.

Pittogrammi

Health hazardExclamation mark

Avvertenze

Danger

Indicazioni di pericolo

Classi di pericolo

Aquatic Chronic 3 - Carc. 1B - Eye Irrit. 2 - Muta. 2 - Skin Irrit. 2 - Skin Sens. 1 - STOT SE 3

Organi bersaglio

Central nervous system

Codice della classe di stoccaggio

6.1D - Non-combustible acute toxic Cat.3 / toxic hazardous materials or hazardous materials causing chronic effects

Classe di pericolosità dell'acqua (WGK)

WGK 3

Punto d’infiammabilità (°F)

closed cup - does not flash

Punto d’infiammabilità (°C)

closed cup - does not flash

Dispositivi di protezione individuale

Eyeshields, Gloves, type ABEK (EN14387) respirator filter


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S Yamazaki et al.
Water research, 35(4), 1022-1028 (2001-03-10)
A recirculating system of aqueous trichloroethylene (TCE) solutions through the packed bed reactor with TiO2 pellets has been developed in order to mineralize TCE without difficulties for filtration and recovery of catalyst. The TiO2 pellets prepared by sol gel method
Anaerobic degradation of trichloroethylene in soil.
Kleopfer RD, et al.
Environmental Science & Technology, 19(3), 277-280 (1985)
E M Waters et al.
Journal of toxicology and environmental health, 2(3), 671-707 (1977-01-01)
Trichloroethylene (TCE) has been an industrial chemical of some importance for the past 50 years. First synthesized by Fischer in 1864, TCE has enjoyed considerable industrial usage as a degreaser and limited medical use as an inhalation anesthetic and analgesic.
Chlorinated Decreasing Solvents: Physical-Chemical Properties Affecting Aquifer Contamination and Remediation.
Jackson RE and Dwarakanath V.
Ground Water Monitoring & Remediation, 19(4), 102-110 (1999)
A L Teel et al.
Water research, 35(4), 977-984 (2001-03-10)
Contaminant degradation, stoichiometry, and role of hydroxyl radicals (OH*) in four Fenton's systems were investigated using trichloroethylene (TCE) as a model contaminant. A standard Fenton's system, a modified soluble iron system with a pulse input of hydrogen peroxide, and two

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