795658

Garg 3,4-pyridyne precursor

97%

• Sinonimo/i: 4-(Trimethylsilyl)pyridin-3-yl trifluoromethanesulfonate
• Formula empirica (notazione di Hill): C₉H₁₂F₃NO₃SSi
• Numero CAS: 1211583-40-2
• Peso molecolare: 299.34
• Numero MDL: MFCD18257070
• Codice UNSPSC: 12352100
• ID PubChem: 329768499
• NACRES: NA.22

Proprietà

• Livello qualitativo: 100
• Saggio: 97%
• Forma fisica: liquid
• Indice di rifrazione: n/D 1.455
• Densità: 1.259 at 25 °C
• Temperatura di conservazione: 2-8°C
• Stringa SMILE: C[Si](C)(C)C1=C(OS(=O)(C(F)(F)F)=O)C=NC=C1
• InChI: 1S/C9H12F3NO3SSi/c1-18(2,3)8-4-5-13-6-7(8)16-17(14,15)9(10,11)12/h4-6H,1-3H3; HJIBLRJECSPWKZ-UHFFFAOYSA-N

Descrizione

Applicazioni

Pyridyne precursor can be activated under mild fluoride conditions; which are highly reactive with dienes and other dipolariphiles (e.g. azides) to provide cycloaddition products containing an indole motif.

Confezionamento

Each Aldrich^CPR product will be packaged in one consolidated unit unless you specify multiple units at the time of order.

Altre note

Indolyne Experimental and Computational Studies: Synthetic Applications and Origins of Selectivities of Nucleophilic Additions

Regioselective reactions of 3; 4-pyridynes enabled by the aryne distortion model

Please note that Sigma-Aldrich provides this product to early discovery researchers as part of a collection of unique chemicals. Sigma-Aldrich does not collect analytical data for this product. Buyer assumes responsibility to confirm product identity and/or purity. All sales are final.

NOTWITHSTANDING ANY CONTRARY PROVISION CONTAINED IN SIGMA-ALDRICH′S STANDARD TERMS AND CONDITIONS OF SALE OR AN AGREEMENT BETWEEN SIGMA-ALDRICH AND BUYER, SIGMA-ALDRICH SELLS THIS PRODUCT "AS-IS" AND MAKES NO REPRESENTATION OR WARRANTY WHATSOEVER WITH RESPECT TO THIS PRODUCT, INCLUDING ANY (A) WARRANTY OF MERCHANTABILITY; (B) WARRANTY OF FITNESS FOR A PARTICULAR PURPOSE; OR (C) WARRANTY AGAINST INFRINGEMENT OF INTELLECTUAL PROPERTY RIGHTS OF A THIRD PARTY; WHETHER ARISING BY LAW, COURSE OF DEALING, COURSE OF PERFORMANCE, USAGE OF TRADE OR OTHERWISE.

Informazioni sulla sicurezza

• Pittogrammi: GHS07
• Avvertenze: Warning
• Indicazioni di pericolo: H315,H319,H335
• Consigli di prudenza: P261 - P264 - P271 - P280 - P302 + P352 - P305 + P351 + P338
• Classi di pericolo: Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
• Organi bersaglio: Respiratory system
• Codice della classe di stoccaggio: 10 - Combustible liquids
• Classe di pericolosità dell'acqua (WGK): WGK 3
• Punto d’infiammabilità (°F): Not applicable
• Punto d’infiammabilità (°C): Not applicable