756741

PCy3 Pd G2

95%

• Sinonimo/i: Chloro[(tricyclohexylphosphine)-2-(2′-aminobiphenyl)]palladium(II), Tricyclohexylphosphine Pd G2
• Formula empirica (notazione di Hill): C₃₀H₄₃ClNPPd
• Numero CAS: 1353658-81-7
• Peso molecolare: 590.52
• Numero MDL: MFCD21363051
• Codice UNSPSC: 12161600
• ID PubChem: 329766615
• NACRES: NA.22

Proprietà

• Saggio: 95%
• Stato: solid
• Caratteristiche: generation 2
• Impiego in reazioni chimiche: core: palladium; reaction type: Buchwald-Hartwig Cross Coupling Reaction; reaction type: C-H Activation; reaction type: Heck Reaction; reaction type: Hiyama Coupling; reaction type: Negishi Coupling; reaction type: Sonogashira Coupling; reaction type: Stille Coupling; reaction type: Suzuki-Miyaura Coupling; reagent type: catalyst; reaction type: Cross Couplings
• Punto di fusione: 244-246 °C
• Gruppo funzionale: phosphine
• Stringa SMILE: NC1=C(C2=C([Pd]Cl)C=CC=C2)C=CC=C1.C3(CCCCC3)P(C4CCCCC4)C5CCCCC5
• InChI: 1S/C18H33P.C12H10N.ClH.Pd/c1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;13-12-9-5-4-8-11(12)10-6-2-1-3-7-10;;/h16-18H,1-15H2;1-6,8-9H,13H2;1H;/q;;;+1/p-1; CYJRABDADOSMKA-UHFFFAOYSA-M

Descrizione

Applicazioni

PCy3 Pd G2 is a monophosphine-coordinated 2-phenylaniline-based palladacycle complex that can be used as a precatalyst:

• To prepare diarylmethanes by Suzuki cross-coupling reaction with heterocyclic-chloromethyl derivatives with aryl/heteroaryl boronic acids.
• To synthesize poly(arylene)s by the Suzuki cross-coupling polymerization reaction between aryl dihalides and aryldiboronic acids.
• In the C-H bond functionalization reactions.

Informazioni sulla sicurezza

• Codice della classe di stoccaggio: 11 - Combustible Solids
• Classe di pericolosità dell'acqua (WGK): WGK 3
• Punto d’infiammabilità (°F): Not applicable
• Punto d’infiammabilità (°C): Not applicable