763314

sSPhos Pd G2

95%

• Sinonimo/i: Chloro(sodium-2-dicyclohexylphosphino-2′,6′-dimethoxy-1,1′-biphenyl-3′-sulfonate)[2-(2′-amino-1,1′-biphenyl)]palladium(II)
• Formula empirica (notazione di Hill): C₃₈H₄₄ClNNaO₅PPdS
• Numero CAS: 2375242-78-5
• Peso molecolare: 822.66
• Numero MDL: MFCD22377809
• Codice UNSPSC: 12161600
• ID PubChem: 329767044
• NACRES: NA.22

Proprietà

• Livello qualitativo: 100
• Saggio: 95%
• Stato: solid
• Caratteristiche: generation 2
• Impiego in reazioni chimiche: core: palladium; reaction type: Buchwald-Hartwig Cross Coupling Reaction; reaction type: Heck Reaction; reaction type: Hiyama Coupling; reaction type: Negishi Coupling; reaction type: Sonogashira Coupling; reaction type: Stille Coupling; reaction type: Suzuki-Miyaura Coupling; reagent type: catalyst; reaction type: Cross Couplings
• Punto di fusione: 193-194 °C (decomposition)
• Gruppo funzionale: phosphine
• Stringa SMILE: [Na+].Nc1ccccc1-c2ccccc2[Pd]Cl.COc3ccc(c(OC)c3-c4ccccc4P(C5CCCCC5)C6CCCCC6)S([O-])(=O)=O
• InChI: 1S/C26H35O5PS.C12H10N.ClH.Na.Pd/c1-30-22-17-18-24(33(27,28)29)26(31-2)25(22)21-15-9-10-16-23(21)32(19-11-5-3-6-12-19)20-13-7-4-8-14-20;13-12-9-5-4-8-11(12)10-6-2-1-3-7-10;;;/h9-10,15-20H,3-8,11-14H2,1-2H3,(H,27,28,29);1-6,8-9H,13H2;1H;;/q;;;2*+1/p-2; MWQYWXJKMDRSJN-UHFFFAOYSA-L

Descrizione

Applicazioni

sSPhos Pd G2 can be used as a water-soluble Pd-precatalyst in:

• DNA-compatible Suzuki-Miyaura reaction between DNA-linked aryl halides and various boronic acids/esters including heteroaryl boronates.
• DNA-compatible hydroxycarbonylation reactions.
• The cross-coupling reaction between boronic ester and brominated cyclic nucleotide to synthesize cyclic adenosine and guanosine monophosphate in the presence of potassium phosphate and hydrochloric acid.

Informazioni sulla sicurezza

• Codice della classe di stoccaggio: 11 - Combustible Solids
• Classe di pericolosità dell'acqua (WGK): WGK 3
• Punto d’infiammabilità (°F): Not applicable
• Punto d’infiammabilità (°C): Not applicable