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709085

Sigma-Aldrich

C60 Pyrrolidine tris-acid

97%

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About This Item

Formula empirica (notazione di Hill):
C66O6NH7
Peso molecolare:
909.76
Codice UNSPSC:
12352103
NACRES:
NA.23

Saggio

97%

Forma fisica

powder

Punto di fusione

>300 °C

Solubilità

water, pH >9: soluble

Descrizione generale

C60 Pyrrolidine tris-acid (CPTA) is a fullerene derivative that has carboxyl functionalized carbon buckyballs. It is majorly used in electrochemical devices as an electron transporting layer (ETL) due to its high energy level and electron mobility. It can be used as an alternative to conventional metal oxide based charge carrying films, through the esterification of a carboxylic acid with hydroxyl groups. Its solubility in water and other polar solvents makes it useful in solution processed devices.
This is a high value compound - minimal loss. It is water soluble fullerene, hence suitable for biological applications. Water-soluble fullerene adduct. Mono-adduct solubility at pH ~13 is about 0.5 mg/ml, giving stable solutions with aggregates in the 20 - 200 nm range. At pH 7.4, solubility is about 0.002 - 0.005 mg/ml.

Applicazioni

C60 Pyrrolidine tris-acid may be used as a cathode buffer layer in solar cells. It may be used as a wetting layer in an organic photovoltaics.
CPTA can be used as a cathodic buffer that forms a conductive layer between the active layer and the electrode layer for the fabrication of polymeric solar cells and perovskite based solar cells.

Pittogrammi

Exclamation mark
GHS07

Avvertenze

Warning

Indicazioni di pericolo

H315,H319,H335

Classi di pericolo

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

Organi bersaglio

Respiratory system

Codice della classe di stoccaggio

11 - Combustible Solids

Classe di pericolosità dell'acqua (WGK)

WGK 3

Dispositivi di protezione individuale

dust mask type N95 (US), Eyeshields, Gloves

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Certificati d'analisi (COA)

Lot/Batch Number
SHBJ8306
SHBD9755V
20096AP
MKBB4677

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[6,6]-Phenyl C61 butyric acid methyl ester ≥99%

Sigma-Aldrich

684449

[6,6]-Phenyl C61 butyric acid methyl ester

Fullerene-C60 98%

Sigma-Aldrich

483036

Fullerene-C60

Efficient and Hysteresis-Free Perovskite Solar Cells Based on a Solution Processable Polar Fullerene Electron Transport Layer
Wang Y, et al.
Advanced Energy Materials, 7(21), 1701144-1701144 (2017)
Probing ultrafast charge separation at organic donor/acceptor interfaces by a femtosecond electric field meter.
Kaake LG, et al.
Applied Physics Letters, 99(8) (2011)
High performance polymer solar cells with a polar fullerene derivative as the cathode buffer layer.
Li X, et al.
Journal of Material Chemistry A, 1(40), 12413-12416 (2013)
Okuda
Fullerene Science and Technology, 8, 89-94 null
Fullerene nanoparticles exhibit greater retention in freshwater sediment than in model porous media.
Zhang W, et al.
Water Research, 46(9), 2992-3004 (2012)
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