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684457

Sigma-Aldrich

[6,6]-Phenyl C61 butyric acid methyl ester

>99.9%

Sinonimo/i:

3′H-Cyclopropa[1,9] [5,6]fullerene-C60-Ih-3′-butanoic acid 3′-phenyl methyl ester, [60]PCBM

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About This Item

Formula empirica (notazione di Hill):
C72H14O2
Numero CAS:
160848-22-6
Peso molecolare:
910.88
Numero MDL:
MFCD07784544
Codice UNSPSC:
12352103
ID PubChem:
24885806
NACRES:
NA.23

Descrizione

functionalized fullerene

Saggio

>99.9%

Forma fisica

solid

Solubilità

chlorobenzene: soluble
organic solvents: soluble
toluene: soluble

Energia dell’orbitale

HOMO 6.1 eV 
LUMO 3.7 eV 

Caratteristiche del semiconduttore

N-type (mobility=0.21 cm2/V·s)

Stringa SMILE

COC(=O)CCCC2(c1ccccc1)[C]3=4c5c6c7c8c9c%10c(c%11c%12c3c%13c5c%14c%15c6c%16c7c%17c9c%18c%19c%10c%20c%11c%21c%12c%22c%13c%23c%14c%24c%15c%25c%16c%26c%17c%18c%27c%28c%19c%20c%29c%21c%30c%22c%23c%31c%24c%32c%25c%26c%27c%33c%28c%29c%30c%31c%32%33)[C]2=48

InChI

1S/C72H14O2/c1-74-11(73)8-5-9-70(10-6-3-2-4-7-10)71-66-59-52-40-32-23-14-12-13-15-18(14)27-34(32)42-43-35(27)33-24(15)26-22-17(13)20-19-16(12)21-25(23)38(40)46-44-30(21)28(19)36-37-29(20)31(22)45-47-39(26)41(33)53-55(43)64(63(66)54(42)52)67-60(53)58(47)62-51(45)49(37)56-48(36)50(44)61(57(46)59)68(71)65(56)69(62)72(67,70)71/h2-4,6-7H,5,8-9H2,1H3
MCEWYIDBDVPMES-UHFFFAOYSA-N

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Descrizione generale

[6,6]-Phenyl C61 butyric acid methyl ester ([60]PCBM) is a methanofullerene that has a better solubility in organic solvents than fullerenes(C60). It has high electron mobility which enables its function as an electron acceptor in electrochemical applications.

Applicazioni

[60]PCBM is an n-type semi-conductor widely used as an electron transport material with low cost and high surface area in different energy based applications like organic photovoltaics (OPVs), perovskite solar cells (PSCs), field effect transistors (FETs) and photodetectors.
Soluble n-channel organic semiconductor. For use as an n-type layer in plastic electronics, especially bulk heterojunction OFETs and photovoltaic cells (PVs).

Codice della classe di stoccaggio

11 - Combustible Solids

Classe di pericolosità dell'acqua (WGK)

WGK 3

Punto d’infiammabilità (°F)

Not applicable

Punto d’infiammabilità (°C)

Not applicable

Dispositivi di protezione individuale

Eyeshields, Gloves, type N95 (US)

Certificati d'analisi (COA)

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PTB7 average Mw 80,000-200,000, PDI ≤3.0

Sigma-Aldrich

772410

PTB7

Enhancement of organic photovoltaic device performance via P3HT: PCBM solution heat treatment.
Otieno F, et al.
Thin Solid Films, 625(24), 62-69 (2017)
Perovskite-fullerene hybrid materials suppress hysteresis in planar diodes.
Xu J, et al.
Nature Communications, 6(7), 7081-7081 (2015)
(60) PCBM single crystals: remarkably enhanced band-like charge transport, broadband UV-visible-NIR photo-responsivity and improved long-term air-stability.
Zhao X, et al.
Journal of Material Chemistry C, 6(20), 5489-5496 (2018)
Organic Single-Crystalline Donor-Acceptor Heterojunctions with Ambipolar Band-Like Charge Transport for Photovoltaics.
Zhao X, et al.
Advanced Materials Interfaces, 530(24), 1800336-1800336 (2018)
Field-effect transistor structures on the basis of poly (3-hexylthiophene), fullerene derivatives (60) PCBM,(70) PCBM, and nickel nanoparticles.
Aleshin N, et al.
Physics of the Solid State, 58(9), 1882-1890 (2016)
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