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449903

Sigma-Aldrich

Lithium fluoride

greener alternative

≥99.99% trace metals basis

Sinonimo/i:

Fluorolithium

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About This Item

Formula condensata:
LiF
Numero CAS:
Peso molecolare:
25.94
Numero CE:
Numero MDL:
Codice UNSPSC:
12352302
ID PubChem:
NACRES:
NA.23

Grado

anhydrous

Livello qualitativo

Saggio

≥99.99% trace metals basis

Forma fisica

powder and chunks

Caratteristiche più verdi

Design for Energy Efficiency
Learn more about the Principles of Green Chemistry.

Impurezze

≤100.0 ppm Trace Metal Analysis

P. eboll.

1673 °C/1 atm (lit.)

Punto di fusione

845 °C (lit.)

Solubilità

aqueous acid: slightly soluble(lit.)

Densità

2.64 g/mL at 25 °C (lit.)

Categoria alternativa più verde

Stringa SMILE

[Li+].[F-]

InChI

1S/FH.Li/h1H;/q;+1/p-1
PQXKHYXIUOZZFA-UHFFFAOYSA-M

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Descrizione generale

Lithium fluoride is a white crystalline solid with a high melting point. It is widely applied in the field of rechargeable batteries, storage devices, and thermoluminescent materials. LiF is also used as a coupling layer in OLED or PLED devices to enhance electron injection. On the other hand, it is preferred for optical applications due to its wide band gap, which allows it to transmit light efficiently.
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Applicazioni

Lithium fluoride can be used:
  • As an additive to fabricate SiO@C/graphite composite anode materials for Li-ion batteries. LiF stabilizes solid electrolyte interphase (SEI) and enhances initial coulombic efficiency.
  • As a critical component in SEI for stabilizing the SEI layer and improving the cycling efficiency of Li metal batteries.
  • To fabricate electron contacts for high-efficiency n-type crystalline silicon solar cells.
  • To prepare solid-state light sources for radiation imaging detectors.
  • To synthesize highly crystalline MXene for asymmetric supercapacitor applications. And also, lightweight, flexible, and hydrophobic MXene foam with reasonable strength, high electrical conductivity, and an outstanding EMI-shielding performance.
  • As an electron-injection layer to fabricate ITO/PEDOT:PSS/perovskite/B3PYMPM/ LiF/Al OLED device with a quantum efficiency of 20%.

Pittogrammi

Skull and crossbones

Avvertenze

Danger

Indicazioni di pericolo

Classi di pericolo

Acute Tox. 3 Oral - Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

Organi bersaglio

Respiratory system

Rischi supp

Codice della classe di stoccaggio

6.1D - Non-combustible, acute toxic Cat.3 / toxic hazardous materials or hazardous materials causing chronic effects

Classe di pericolosità dell'acqua (WGK)

WGK 2

Punto d’infiammabilità (°F)

Not applicable

Punto d’infiammabilità (°C)

Not applicable

Dispositivi di protezione individuale

Eyeshields, Faceshields, Gloves, type P2 (EN 143) respirator cartridges


Certificati d'analisi (COA)

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The performances of organometallic halide perovskite-based solar cells severely depend on the device architecture and the interface between each layer included in the device stack. In particular, the interface between the charge transporting layer and the perovskite film is crucial
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