434191
Vinyl bromide solution
1.0 M in THF
Sinonimo/i:
Bromoethylene
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About This Item
Formula condensata:
CH2=CHBr
Numero CAS:
Peso molecolare:
106.95
Beilstein:
1361370
Numero MDL:
Codice UNSPSC:
12162002
ID PubChem:
NACRES:
NA.23
Prodotti consigliati
Tensione di vapore
12.46 psi ( 55 °C)
3.6 psi ( 20 °C)
Forma fisica
liquid
Concentrazione
1.0 M in THF
Densità
0.927 g/mL at 25 °C
Temperatura di conservazione
2-8°C
Stringa SMILE
BrC=C
InChI
1S/C2H3Br/c1-2-3/h2H,1H2
INLLPKCGLOXCIV-UHFFFAOYSA-N
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Categorie correlate
Descrizione generale
Vinyl bromide solution belongs to haloalkenes andis highly reactive due to the presence of an unsaturated vinyl group. It can provide flame retardancy to polymers or materials when incorporated into their structure. It is also a versatile building block for polymerization, addition reactions, substitution reactions, and cross-coupling reactions like Suzuki-Miyaura and Negishi reactions. It can be used to introduce radiolabel into molecules for medical imaging.
Applicazioni
- Sequential Vinyl Radical Cyclization/Fixation of Carbon Dioxide through Electrochemical Reduction of Vinyl Bromide in the Presence of an Electron-Transfer Mediator: This study explores the electrochemical reduction of vinyl bromide with a focus on vinyl radical cyclization and carbon dioxide fixation (A Katayama, H Senboku, 2016).
- A Comparison of the Wavelength-Dependent Photochemical Reactions of Ozone with Vinyl Bromide and Fluoride in Argon Matrices: The study compares the photochemical reactions of vinyl bromide and fluoride with ozone, examining their behavior in argon matrices (BS Ault, 2021).
Vinyl bromide solution can be used as a precursor for stereoselective synthesis of chiral 2-vinyl-tetrahydronaphthalens via asymmetric reductive coupling. These chiral compounds are valuable building blocks for natural products, agrochemicals, and liquid crystals.
Avvertenze
Danger
Indicazioni di pericolo
Consigli di prudenza
Classi di pericolo
Acute Tox. 4 Oral - Carc. 1B - Eye Irrit. 2 - Flam. Liq. 2 - STOT SE 3
Organi bersaglio
Central nervous system, Respiratory system
Rischi supp
Codice della classe di stoccaggio
3 - Flammable liquids
Classe di pericolosità dell'acqua (WGK)
WGK 3
Punto d’infiammabilità (°F)
1.4 °F - closed cup
Punto d’infiammabilità (°C)
-17 °C - closed cup
Dispositivi di protezione individuale
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
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